Jun-Hao Wu, Xin-Hui Lu, Qian-Qian Yan, Ji-Xia Qiu, Wei Zhou, Yuan-Yuan Zhu, Xiao Wang, Sheng Zhang, Kui Li, Xing Lu
{"title":"Inside Front Cover: Staggered ABC-Stacking Cobalt-Triptycene Framework for Accelerating CO2 Photoreduction (Angew. Chem. 29/2025)","authors":"Jun-Hao Wu, Xin-Hui Lu, Qian-Qian Yan, Ji-Xia Qiu, Wei Zhou, Yuan-Yuan Zhu, Xiao Wang, Sheng Zhang, Kui Li, Xing Lu","doi":"10.1002/ange.202513693","DOIUrl":null,"url":null,"abstract":"<p>The cover illustrates the catalytic mechanism of a cobalt-triptycene framework with ABC stacking for the photocatalytic reduction of CO<sub>2</sub> to CO and H<sub>2</sub>. Uniformly distributed Co sites along the pore walls and the ABC stacking facilitate molecular diffusion, thereby accelerating the photocatalytic reaction. The framework regulates the transport of CO<sub>2</sub>, H<sub>2</sub>O, and *COOH intermediates, while hydrogen bonding between H<sub>2</sub>O and CO<sub>2</sub> coupled with carbonate formation enriches CO<sub>2</sub> concentration at metal active sites, promoting the reduction process, as reported by Wei Zhou, Xiao Wang, Xing Lu et al. in their Research Article (e202504155).\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 29","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202513693","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202513693","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The cover illustrates the catalytic mechanism of a cobalt-triptycene framework with ABC stacking for the photocatalytic reduction of CO2 to CO and H2. Uniformly distributed Co sites along the pore walls and the ABC stacking facilitate molecular diffusion, thereby accelerating the photocatalytic reaction. The framework regulates the transport of CO2, H2O, and *COOH intermediates, while hydrogen bonding between H2O and CO2 coupled with carbonate formation enriches CO2 concentration at metal active sites, promoting the reduction process, as reported by Wei Zhou, Xiao Wang, Xing Lu et al. in their Research Article (e202504155).