Frontispiece: Imidazo[1,5-a]pyridines – A Versatile Platform for Structurally Distinct N-Heterocyclic Olefins and π-Extended Heterocycles

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Abstract

An island of unusual electronic properties: In their Communication (e202506305), Max M. Hansmann et al. design a new platform for N-heterocyclic olefins, their unique intramolecular cyclization and the paratropic ring current of the tricyclic products, represented by dolphins jumping in between the quinolizine ring. The follow-up oxidation leads to a stable fluorescent organic radical.

Abstract Image

前言:咪唑[1,5- A]吡啶-结构不同的n -杂环烯烃和π-扩展杂环的通用平台
一个不寻常的电子性质岛:在他们的Communication (e202506305)中,Max M. Hansmann等人设计了一个新的n -杂环烯烃平台,其独特的分子内环化和三环产物的异向环电流,以海豚在喹啉环之间跳跃为代表。后续氧化产生稳定的荧光有机自由基。
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来源期刊
Angewandte Chemie
Angewandte Chemie 化学科学, 有机化学, 有机合成
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