Long-Term Durability of CFRP Strips Used in Infrastructure Rehabilitation.

IF 4.7 3区 工程技术 Q1 POLYMER SCIENCE
Polymers Pub Date : 2025-07-07 DOI:10.3390/polym17131886
Karunya Kanagavel, Vistasp M Karbhari
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引用次数: 0

Abstract

Prefabricated unidirectional carbon fiber reinforced polymer (CFRP) composite strips are extensively used as a means of infrastructure rehabilitation through adhesive bonding to the external surface of structural concrete elements. Most data to date are from laboratory tests ranging from a few months to 1-2 years providing an insufficient dataset for prediction of long-term durability. This investigation focuses on the assessment of the response of three different prefabricated CFRP systems exposed to water, seawater, and alkaline solutions for 5 years of immersion in deionized water conducted at three temperatures of 23, 37.8 and 60 °C, all well below the glass transition temperature levels. Overall response is characterized through tensile and short beam shear (SBS) testing at periodic intervals. It is noted that while the three systems are similar, with the dominant mechanisms of deterioration being related to matrix plasticization followed by fiber-matrix debonding with levels of matrix and interface deterioration being accelerated at elevated temperatures, their baseline characteristics and distributions are different emphasizing the need for greater standardization. While tensile modulus does not degrade appreciably over the 5-year period of exposure with final levels of deterioration being between 7.3 and 11.9%, both tensile strength and SBS strength degrade substantially with increasing levels based on temperature and time of immersion. Levels of tensile strength retention can be as low as 61.8-66.6% when immersed in deionized water at 60 °C, those for SBS strength can be 38.4-48.7% at the same immersion condition for the three FRP systems. Differences due to solution type are wider in the short-term and start approaching asymptotic levels within FRP systems at longer periods of exposure. The very high levels of deterioration in SBS strength indicate the breakdown of the materials at the fiber-matrix bond and interfacial levels. It is shown that the level of deterioration exceeds that presumed through design thresholds set by specific codes/standards and that new safety factors are warranted in addition to expanding the set of characteristics studied to include SBS or similar interface-level tests. Alkali solutions are also shown to have the highest deteriorative effects with deionized water having the least. Simple equations are developed to enable extrapolation of test data to predict long term durability and to develop design thresholds based on expectations of service life with an environmental factor of between 0.56 and 0.69 for a 50-year expected service life.

CFRP条在基础设施修复中的长期耐久性研究
预制单向碳纤维增强聚合物(CFRP)复合条通过粘接在结构混凝土构件的外表面,被广泛用作基础设施修复的手段。迄今为止,大多数数据来自实验室测试,时间从几个月到1-2年不等,因此无法提供足够的数据集来预测长期耐久性。本研究的重点是评估三种不同的预制CFRP系统在23、37.8和60℃三种温度下暴露于水、海水和碱性溶液中5年的反应,这些温度都远低于玻璃化转变温度水平。通过周期性的拉伸和短梁剪切(SBS)测试来表征整体响应。值得注意的是,虽然这三种体系相似,但主要的劣化机制与基体塑化有关,随后是纤维-基体脱粘,在高温下基体和界面劣化水平加速,但它们的基线特征和分布不同,强调需要更大的标准化。虽然拉伸模量在5年的暴露期间不会明显下降,最终下降水平在7.3到11.9%之间,但拉伸强度和SBS强度都随着浸泡温度和时间的增加而大幅下降。在60℃去离子水浸泡条件下,三种FRP体系的抗拉强度保持率可低至61.8 ~ 66.6%,SBS强度保持率可达38.4 ~ 48.7%。溶液类型造成的差异在短期内更大,并在较长暴露时间内开始接近FRP系统的渐近水平。SBS强度的急剧下降表明材料在纤维-基体结合层和界面层发生了破坏。结果表明,恶化程度超过了特定规范/标准设定的设计阈值所假定的程度,因此,除了扩大所研究的特性集以包括SBS或类似的接口级测试外,还需要新的安全因素。碱溶液也被证明具有最高的变质作用,而去离子水具有最小的变质作用。开发了简单的方程式,可以根据测试数据进行外推,以预测长期耐久性,并根据预期使用寿命(环境因子在0.56至0.69之间,预期使用寿命为50年)制定设计阈值。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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