Zeolitic Octahedral Metal Oxides for Catalysis

IF 2.2 4区 化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR
Zhuoyuan Chen, Zhenxin Zhang
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引用次数: 0

Abstract

Zeolitic octahedral metal oxides (ZOMOs) are crystalline microporous transition metal oxides, built from transition metal-oxygen clusters and inorganic linkers. The material shows both microporosity and redox property, which processes both advantages of zeolites and transition metal oxides. This concept outlines five ZOMO frameworks (ZOMO-1 to ZOMO-5) with tunable pore geometries and elemental diversity, enabling to tune the structure and chemical composition, which leads to tuning the catalytic activity of the materials. ZOMOs exhibit exceptional catalytic performance in selective oxidation, oxidative degradation, and H2 evolution. Despite progress, there are still challenges in structure diversity and atomic-level structural control in the field of ZOMOs. Addressing these will advance ZOMOs as sustainable catalysts for energy and environmental applications.

Abstract Image

催化用沸石八面体金属氧化物
沸石八面体金属氧化物(ZOMOs)是由过渡金属-氧团簇和无机连接剂构成的结晶微孔过渡金属氧化物。该材料具有微孔性和氧化还原性,同时具有沸石和过渡金属氧化物的优点。这个概念概述了五种ZOMO框架(ZOMO-1到ZOMO-5),它们具有可调的孔隙几何形状和元素多样性,能够调整结构和化学成分,从而调整材料的催化活性。ZOMOs在选择性氧化、氧化降解和H2演化中表现出优异的催化性能。尽管取得了进展,但在结构多样性和原子级结构控制方面仍存在挑战。解决这些问题将推动zomo成为能源和环境应用的可持续催化剂。
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来源期刊
European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry 化学-无机化学与核化学
CiteScore
4.30
自引率
4.30%
发文量
419
审稿时长
1.3 months
期刊介绍: The European Journal of Inorganic Chemistry (2019 ISI Impact Factor: 2.529) publishes Full Papers, Communications, and Minireviews from the entire spectrum of inorganic, organometallic, bioinorganic, and solid-state chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form the two leading journals, European Journal of Inorganic Chemistry and European Journal of Organic Chemistry: Chemische Berichte Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry The European Journal of Inorganic Chemistry continues to keep you up-to-date with important inorganic chemistry research results.
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