Influence of carbon black and cotton fiber on the mechanical and thermal properties of natural rubber composites: a statistical optimization using Central composite design
{"title":"Influence of carbon black and cotton fiber on the mechanical and thermal properties of natural rubber composites: a statistical optimization using Central composite design","authors":"Sumit Kumar , Sohan Lal , Sanjiv Arora , Parvin Kumar , Shikha Rani , Anjali Verma , Anita Kumari","doi":"10.1080/1023666X.2025.2495283","DOIUrl":null,"url":null,"abstract":"<div><div>The objective of this study is to enhance the thermal as well as the mechanical properties of vulcanized natural rubber with hybrid reinforcement including alkali-treated cotton fiber and carbon black. The central composite design and response surface methodology techniques were employed to design the experiment and examine optimum mechanical strength with corresponding optimum reinforcement composition. The tensile strength of composites increased from 1.71 to 18.87 MPa as a result of reinforcement. Likewise, the tear strength was improved from 23.20 to 57.91 N/mm. The thermal stability of the composites gets enhanced with the addition of carbon black from 320 °C to 343 °C. FTIR and SEM analysis revealed intercomponent interactions and surface texture of prepared composites. The hybrid reinforcement of cotton fiber and carbon black in the rubber matrix brings out enhancement in mechanical properties as well as the thermal stability of the final composite material. A minute increment in the density of samples was noticed with the addition of cotton fiber and carbon black in the rubber matrix. This increase in density is significantly less than the increase in mechanical strength of composites, which is a good parameter for application purposes of composites.</div></div>","PeriodicalId":14236,"journal":{"name":"International Journal of Polymer Analysis and Characterization","volume":"30 5","pages":"Pages 563-580"},"PeriodicalIF":1.6000,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Polymer Analysis and Characterization","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1023666X25000265","RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
The objective of this study is to enhance the thermal as well as the mechanical properties of vulcanized natural rubber with hybrid reinforcement including alkali-treated cotton fiber and carbon black. The central composite design and response surface methodology techniques were employed to design the experiment and examine optimum mechanical strength with corresponding optimum reinforcement composition. The tensile strength of composites increased from 1.71 to 18.87 MPa as a result of reinforcement. Likewise, the tear strength was improved from 23.20 to 57.91 N/mm. The thermal stability of the composites gets enhanced with the addition of carbon black from 320 °C to 343 °C. FTIR and SEM analysis revealed intercomponent interactions and surface texture of prepared composites. The hybrid reinforcement of cotton fiber and carbon black in the rubber matrix brings out enhancement in mechanical properties as well as the thermal stability of the final composite material. A minute increment in the density of samples was noticed with the addition of cotton fiber and carbon black in the rubber matrix. This increase in density is significantly less than the increase in mechanical strength of composites, which is a good parameter for application purposes of composites.
期刊介绍:
The scope of the journal is to publish original contributions and reviews on studies, methodologies, instrumentation, and applications involving the analysis and characterization of polymers and polymeric-based materials, including synthetic polymers, blends, composites, fibers, coatings, supramolecular structures, polysaccharides, and biopolymers. The Journal will accept papers and review articles on the following topics and research areas involving fundamental and applied studies of polymer analysis and characterization:
Characterization and analysis of new and existing polymers and polymeric-based materials.
Design and evaluation of analytical instrumentation and physical testing equipment.
Determination of molecular weight, size, conformation, branching, cross-linking, chemical structure, and sequence distribution.
Using separation, spectroscopic, and scattering techniques.
Surface characterization of polymeric materials.
Measurement of solution and bulk properties and behavior of polymers.
Studies involving structure-property-processing relationships, and polymer aging.
Analysis of oligomeric materials.
Analysis of polymer additives and decomposition products.