Volker Klein, Florian Schuster, Jonas Amthor, Harald Maid, Prabhakar Bijalwan, Fahmi Himo, Stefano Santoro, Svetlana B. Tsogoeva
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引用次数: 0
Abstract
Organoautocatalyzed transamination metathesis of challenging cyclic tertiary amines is reported. In their Research Article (e202505275), Svetlana B. Tsogoeva and co-workers demonstrate the use of an in situ-formed pyrrolidinium salt as an efficient organoautocatalyst, enabling double C(sp2)-N bond metathesis at room temperature via a domino reaction mechanism. This metal- and additive-free transformation advances green, waste-reducing, and sustainable approaches in organic synthesis.
报道了具有挑战性的环叔胺的有机自催化转氨化。在他们的研究文章（e2012505275）中，Svetlana B. Tsogoeva及其同事展示了使用原位形成的吡咯烷盐作为有效的有机自催化剂，通过多米诺反应机制在室温下实现双C(sp2)-N键的转化。这种不含金属和添加剂的转变推进了绿色、减少废物和可持续的有机合成方法。
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