S. Arunkumar, Gokul Raj Mini Rajendran, Aniket Chowdhury, George Rajendra Kumar
{"title":"Dicyanovinyl Appended Carbazole Based Colorimetric Sensor for Volatile Organic Amines","authors":"S. Arunkumar, Gokul Raj Mini Rajendran, Aniket Chowdhury, George Rajendra Kumar","doi":"10.1002/anse.202400109","DOIUrl":null,"url":null,"abstract":"<p>Herein we report synthesis, photophysical properties and amine sensing applications of a carbazole-dicyanovinyl based sensor (<b>2</b>). Sensor molecule <b>2</b> shows solid state fluorescence (φ=~41 %), mechanochromic fluorescence and aggregation induced emission. Presence of donor and acceptor groups in <b>2</b> resulted in strong absorption bands in the visible region of electromagnetic spectrum which is exploited for colorimetric sensing of primary amines. Amine sensing mechanism of <b>2</b> is established using <sup>1</sup>H NMR titration studies. Test kit developed using probe <b>2</b> showed prominent color change in presence of biogenic amines generated from decomposed meat product.</p>","PeriodicalId":72192,"journal":{"name":"Analysis & sensing","volume":"5 4","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analysis & sensing","FirstCategoryId":"1085","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/anse.202400109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Herein we report synthesis, photophysical properties and amine sensing applications of a carbazole-dicyanovinyl based sensor (2). Sensor molecule 2 shows solid state fluorescence (φ=~41 %), mechanochromic fluorescence and aggregation induced emission. Presence of donor and acceptor groups in 2 resulted in strong absorption bands in the visible region of electromagnetic spectrum which is exploited for colorimetric sensing of primary amines. Amine sensing mechanism of 2 is established using 1H NMR titration studies. Test kit developed using probe 2 showed prominent color change in presence of biogenic amines generated from decomposed meat product.