Dicyanovinyl Appended Carbazole Based Colorimetric Sensor for Volatile Organic Amines

IF 2.9 Q2 CHEMISTRY, ANALYTICAL
S. Arunkumar, Gokul Raj Mini Rajendran, Aniket Chowdhury, George Rajendra Kumar
{"title":"Dicyanovinyl Appended Carbazole Based Colorimetric Sensor for Volatile Organic Amines","authors":"S. Arunkumar,&nbsp;Gokul Raj Mini Rajendran,&nbsp;Aniket Chowdhury,&nbsp;George Rajendra Kumar","doi":"10.1002/anse.202400109","DOIUrl":null,"url":null,"abstract":"<p>Herein we report synthesis, photophysical properties and amine sensing applications of a carbazole-dicyanovinyl based sensor (<b>2</b>). Sensor molecule <b>2</b> shows solid state fluorescence (φ=~41 %), mechanochromic fluorescence and aggregation induced emission. Presence of donor and acceptor groups in <b>2</b> resulted in strong absorption bands in the visible region of electromagnetic spectrum which is exploited for colorimetric sensing of primary amines. Amine sensing mechanism of <b>2</b> is established using <sup>1</sup>H NMR titration studies. Test kit developed using probe <b>2</b> showed prominent color change in presence of biogenic amines generated from decomposed meat product.</p>","PeriodicalId":72192,"journal":{"name":"Analysis & sensing","volume":"5 4","pages":""},"PeriodicalIF":2.9000,"publicationDate":"2025-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analysis & sensing","FirstCategoryId":"1085","ListUrlMain":"https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/anse.202400109","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Herein we report synthesis, photophysical properties and amine sensing applications of a carbazole-dicyanovinyl based sensor (2). Sensor molecule 2 shows solid state fluorescence (φ=~41 %), mechanochromic fluorescence and aggregation induced emission. Presence of donor and acceptor groups in 2 resulted in strong absorption bands in the visible region of electromagnetic spectrum which is exploited for colorimetric sensing of primary amines. Amine sensing mechanism of 2 is established using 1H NMR titration studies. Test kit developed using probe 2 showed prominent color change in presence of biogenic amines generated from decomposed meat product.

Abstract Image

Abstract Image

Abstract Image

Abstract Image

双氰乙烯基附加咔唑基挥发性有机胺比色传感器
本文报道了一种咔唑-二氰乙烯基传感器的合成、光物理性质和胺传感应用(2)。传感器分子2表现出固态荧光(φ=~ 41%)、机械致变色荧光和聚集诱导发光。2中供体和受体基团的存在导致电磁波谱可见区有很强的吸收带,用于伯胺的比色检测。利用1H NMR滴定法建立了2的胺感机制。使用探针2开发的测试试剂盒显示,分解肉制品产生的生物胺存在显著的颜色变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
CiteScore
2.60
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信