Experimental investigation on the physical and mechanical properties of metakaolin-based geopolymers: Effects of aging and confining pressure

IF 5.8 2区 地球科学 Q2 CHEMISTRY, PHYSICAL
Wei Xu , Matthieu Briffaut , Nicolas Gay , Jianfu Shao
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引用次数: 0

Abstract

Geopolymers are more and more investigated as a promising and sustainable green concrete solution for many engineering applications. A thorough characterization of their physical and mechanical properties is crucial for safety and durability analysis of related structures. This paper investigates the physical and mechanical behaviors of metakaolin-based geopolymer at different ages under uniaxial and triaxial compression conditions. The present study first focuses on the setting time, bulk density, porosity, permeability, and pore structure of selected geopolymer specimens. The emphasis is then placed on the characterization of elastic properties, failure strength and patterns of material through uniaxial and triaxial compression tests. The study reveals that with increasing curing age, the bulk density, porosity, pore volume, and permeability decrease, while one obtains an increase of failure strength, Young’s modulus, internal cohesion, and friction angle. Higher confining pressure enhances failure strength and ductility, shifts cracking mode from axial splitting to inclined shearing, and induces irreversible pore structure changes. Permeability and mechanical behavior show nonlinear dependence on confining pressure. These results bring some new insights on the effects of age and confining pressure on the microstructure, mechanical and transport properties of metakaolin-based geopolymers, potentially supporting engineering design and modeling.
偏高岭土聚合物物理力学性能的实验研究:老化和围压的影响
地聚合物作为一种前景广阔、可持续发展的绿色混凝土解决方案,在许多工程应用中得到了越来越多的研究。全面表征其物理力学性能对相关结构的安全性和耐久性分析至关重要。研究了偏高岭土聚合物在单轴和三轴压缩条件下不同龄期的物理力学行为。本研究首先对所选地聚合物样品的凝结时间、容重、孔隙度、渗透率和孔隙结构进行了研究。然后,重点放在通过单轴和三轴压缩试验表征材料的弹性特性、破坏强度和模式。研究表明,随着龄期的增加,混凝土的容重、孔隙率、孔隙体积和渗透率降低,破坏强度、杨氏模量、内黏聚力和摩擦角增加;高围压提高了破坏强度和延性,使开裂模式由轴向劈裂转变为斜剪,并引起不可逆的孔隙结构变化。渗透率和力学性能与围压呈非线性关系。这些结果为年龄和围压对偏高岭土聚合物的微观结构、力学和输运特性的影响提供了一些新的见解,可能为工程设计和建模提供支持。
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来源期刊
Applied Clay Science
Applied Clay Science 地学-矿物学
CiteScore
10.30
自引率
10.70%
发文量
289
审稿时长
39 days
期刊介绍: Applied Clay Science aims to be an international journal attracting high quality scientific papers on clays and clay minerals, including research papers, reviews, and technical notes. The journal covers typical subjects of Fundamental and Applied Clay Science such as: • Synthesis and purification • Structural, crystallographic and mineralogical properties of clays and clay minerals • Thermal properties of clays and clay minerals • Physico-chemical properties including i) surface and interface properties; ii) thermodynamic properties; iii) mechanical properties • Interaction with water, with polar and apolar molecules • Colloidal properties and rheology • Adsorption, Intercalation, Ionic exchange • Genesis and deposits of clay minerals • Geology and geochemistry of clays • Modification of clays and clay minerals properties by thermal and physical treatments • Modification by chemical treatments with organic and inorganic molecules(organoclays, pillared clays) • Modification by biological microorganisms. etc...
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