Study on the influence of different factors on the direct treatment of high turbidity water by microfiltration processes

IF 4.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
RSC Advances Pub Date : 2025-07-03 DOI:10.1039/D5RA01817J
Xiaosan Song, Ping Li, Qingchao Shen, Wenxuan Wei and Hairong Yan
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引用次数: 0

Abstract

Currently, traditional high turbidity water treatment technologies (coagulation–sedimentation–filtration) face issues such as non-compliant effluent quality, sediment compaction, and poor sludge discharge. Meanwhile, membrane filtration technology suffers from severe membrane fouling in high turbidity water treatment. Therefore, the development of green and low-carbon high turbidity water treatment technologies is urgently needed. This study employs microfiltration to directly filter high turbidity water, investigating turbidity, filtration methods, and transmembrane pressure difference to elucidate the mechanisms of mitigating membrane fouling in high turbidity water treatment. The results indicate that both excessively high and low influent turbidity are detrimental to high turbidity water treatment. Low turbidity fails to effectively protect the membrane, exacerbating membrane fouling, while high turbidity leads to excessive cake layer thickness, reducing membrane flux. Therefore, the optimal treatment turbidity must be determined based on the specifications of the experimental setup. In this study, the optimal treatment turbidity is 900 NTU. Under constant pressure conditions, cross-flow filtration effectively controls the thickness of the filter cake layer, mitigates membrane fouling, and maintains a high membrane flux. When the influent turbidity is 900 NTU, the membrane flux recovery rate and filtration flux are 80.14% and 0.9077 m h−1, respectively, with irreversible membrane fouling being only 0.97 × 1010 m−1. At a constant influent turbidity, higher transmembrane pressure difference increases the filtration flux but exacerbates membrane fouling. When the pressure increases from 6.67 kPa to 33.33 kPa, irreversible membrane fouling increases by 27.97%, while the filtration flux increases by 116.91%. At a pressure of 13.33 kPa, although the filtration flux is 56.83% of that at 33.33 kPa, the irreversible membrane fouling is only 62.25%. Therefore, this study identifies 13.33 kPa as the optimal transmembrane pressure difference. The Hermia model revealed that transmembrane pressure difference was the primary factor aggravating membrane fouling. Finally, through dosing FeCl3 as a coagulant for cake layer regulation, the cake layer structure formed at 15 mg per L dosage showed optimal pollutant interception and removal efficiency: humic acid (HA) removal efficiency reached 75.86% in actual water sources with 79.06% flux recovery rate; simulated feed water achieved 77.44% HA removal with 84.31% flux recovery rate. This study aims to provide reference for microfiltration processes in direct treatment of high-turbidity water.

Abstract Image

不同因素对微滤工艺直接处理高浊度水的影响研究
目前,传统的高浊度水处理技术(混凝-沉淀-过滤)面临出水水质不达标、沉积物压实、污泥排放差等问题。同时,膜过滤技术在高浊度水处理中存在严重的膜污染问题。因此,迫切需要发展绿色低碳高浊度水处理技术。本研究采用微滤直接过滤高浊度水,通过对浊度、过滤方法、跨膜压差等方面的研究,阐明高浊度水处理中膜污染的缓解机理。结果表明,进水浊度过高和过低都不利于高浊度水的处理。低浊度不能有效保护膜,加重膜污染,而高浊度导致滤饼层厚度过大,降低膜通量。因此,最佳处理浊度必须根据实验装置的规格来确定。本研究的最佳处理浊度为900 NTU。在恒压条件下,横流过滤有效控制滤饼层厚度,减轻膜污染,保持较高的膜通量。进水浊度为900 NTU时,膜通量回收率为80.14%,过滤通量为0.9077 m h−1,不可逆膜污染仅为0.97 × 1010 m−1。在一定的进水浊度下,较高的跨膜压差增加了过滤通量,但加剧了膜污染。当压力由6.67 kPa增加到33.33 kPa时,不可逆膜污染增加了27.97%,过滤通量增加了116.91%。在13.33 kPa压力下,虽然过滤通量为33.33 kPa时的56.83%,但不可逆膜污染仅为62.25%。因此,本研究确定13.33 kPa为最佳跨膜压差。Hermia模型表明,膜间压差是造成膜污染的主要因素。最后,通过投加FeCl3作为混凝剂调控滤饼层,在15 mg / L投加量下形成的滤饼层结构表现出最佳的污染物截留和去除效率:在实际水源中腐植酸(HA)去除率达到75.86%,通量回收率达到79.06%;模拟给水HA去除率77.44%,通量回收率84.31%。本研究旨在为微滤工艺直接处理高浊度水提供参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
RSC Advances
RSC Advances chemical sciences-
CiteScore
7.50
自引率
2.60%
发文量
3116
审稿时长
1.6 months
期刊介绍: An international, peer-reviewed journal covering all of the chemical sciences, including multidisciplinary and emerging areas. RSC Advances is a gold open access journal allowing researchers free access to research articles, and offering an affordable open access publishing option for authors around the world.
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