Unlocking scandium from red mud: A critical review of challenges, opportunities, and recovery methods

IF 4.8 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING
Hari S. Jammulamadaka, Mohammad Rezaee, Sarma V. Pisupati
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引用次数: 0

Abstract

Red mud, the fine iron-rich residue generated during the processing of bauxite using the Bayer process, is a highly alkaline hazardous waste with significant environmental implications. While it is predominantly stored in landfills, only a small fraction is repurposed, such as in construction materials. Notably, red mud contains elevated concentrations of Scandium, a critical mineral with growing industrial demand. Over the past few decades, numerous methods have been investigated for scandium recovery from red mud. However, no commercial processes have yet been implemented at scale. This review critically examines these methods, emphasizing the influence of iron on scandium recovery. It concludes by outlining three promising scandium recovery approaches: (i) reduction roasting followed by acid baking and water leaching of the slag, (ii) acid-baking combined with ball-mill assisted water leaching, and (iii) two-stage acid-baking and water leaching.

Abstract Image

从赤泥中提取钪:挑战、机遇和回收方法综述
赤泥是拜耳法处理铝土矿过程中产生的富铁残渣,是一种高碱性的危险废物,具有重大的环境影响。虽然它主要储存在垃圾填埋场,但只有一小部分被重新利用,例如在建筑材料中。值得注意的是,赤泥中钪的含量较高,钪是一种工业需求不断增长的关键矿物。在过去的几十年里,人们研究了许多从赤泥中回收钪的方法。然而,目前还没有大规模实施商业流程。本文综述了这些方法,强调了铁对钪回收的影响。最后概述了三种有前途的钪回收方法:(i)还原焙烧,然后对渣进行酸焙烧和水浸,(ii)酸焙烧结合球磨机辅助水浸,以及(iii)两阶段酸焙烧和水浸。
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来源期刊
Hydrometallurgy
Hydrometallurgy 工程技术-冶金工程
CiteScore
9.50
自引率
6.40%
发文量
144
审稿时长
3.4 months
期刊介绍: Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties. Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.
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