Hari S. Jammulamadaka, Mohammad Rezaee, Sarma V. Pisupati
{"title":"Unlocking scandium from red mud: A critical review of challenges, opportunities, and recovery methods","authors":"Hari S. Jammulamadaka, Mohammad Rezaee, Sarma V. Pisupati","doi":"10.1016/j.hydromet.2025.106522","DOIUrl":null,"url":null,"abstract":"<div><div>Red mud, the fine iron-rich residue generated during the processing of bauxite using the Bayer process, is a highly alkaline hazardous waste with significant environmental implications. While it is predominantly stored in landfills, only a small fraction is repurposed, such as in construction materials. Notably, red mud contains elevated concentrations of Scandium, a critical mineral with growing industrial demand. Over the past few decades, numerous methods have been investigated for scandium recovery from red mud. However, no commercial processes have yet been implemented at scale. This review critically examines these methods, emphasizing the influence of iron on scandium recovery. It concludes by outlining three promising scandium recovery approaches: (i) reduction roasting followed by acid baking and water leaching of the slag, (ii) acid-baking combined with ball-mill assisted water leaching, and (iii) two-stage acid-baking and water leaching.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":"236 ","pages":"Article 106522"},"PeriodicalIF":4.8000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hydrometallurgy","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304386X25000878","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
Red mud, the fine iron-rich residue generated during the processing of bauxite using the Bayer process, is a highly alkaline hazardous waste with significant environmental implications. While it is predominantly stored in landfills, only a small fraction is repurposed, such as in construction materials. Notably, red mud contains elevated concentrations of Scandium, a critical mineral with growing industrial demand. Over the past few decades, numerous methods have been investigated for scandium recovery from red mud. However, no commercial processes have yet been implemented at scale. This review critically examines these methods, emphasizing the influence of iron on scandium recovery. It concludes by outlining three promising scandium recovery approaches: (i) reduction roasting followed by acid baking and water leaching of the slag, (ii) acid-baking combined with ball-mill assisted water leaching, and (iii) two-stage acid-baking and water leaching.
期刊介绍:
Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties.
Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.