Direct Transformation of Biomass into Levulinic Acid Using Acidic Ionic Liquids: An Example of Sustainable and Efficient Waste Valorization.

Abstract

The intensification of the use and conversion of renewable raw materials, including plant biomass, into valuable products is one of the major goals of the Sustainable Development Strategy. Levulinic acid (LA), classified as one of the top twelve biobased platform chemicals of the future, can be produced from lignocellulose; however, this process is often complex. In this work, a novel and effective pathway for the direct transformation of lignocellulosic biomass into LA under mild conditions, without pretreatment, is presented. Selected waste lignocellulosic biomass, including sawmill chips, grass, and walnut waste, as well as model cellulose, were converted to LA using acidic ionic liquids (ILs). Among the evaluated ILs, [Hmim(HSO4)(H2SO4)2] provided the highest product yields even at 50-70°C. The ILs used in this study were significantly more efficient in converting cellulose and biomass compared to conventional sulfuric acid. The highest yield of LA was obtained from sawmill chips, reaching 64.04 mol% of LA.