Depletion effect in an active chiral system†

IF 2.9 3区 化学 Q3 CHEMISTRY, PHYSICAL
Soft Matter Pub Date : 2025-06-30 DOI:10.1039/D5SM00361J
Bharti Dabra and Harsh Soni
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引用次数: 0

Abstract

We investigate the dynamics of ring-shaped chiral particles immersed in a monolayer of hard spherical beads, confined between two vertically vibrating plates. At high bead concentrations, we observe depletion-like attraction between the rings in both co-rotating and counter-rotating configurations, leading to the formation of a dimer. Notably, the range of this interaction extends over several bead diameters, in contrast to passive systems where interactions are typically limited to the particle size. More intriguingly, at low bead concentrations, the rings exhibit mutual repulsion in both cases, which we attribute to a localized high bead concentration between them—suggesting a mechanism opposite to conventional depletion interactions. Additionally, we examine the diffusive properties of dimerized rings and compare them with those of an isolated ring. While the angular diffusion of the dimer is significantly suppressed compared to that of a single ring, its translational diffusion remains nearly unchanged.

Abstract Image

活性手性体系中的耗竭效应。
我们研究了环形手性粒子浸入单层硬球珠中,被限制在两个垂直振动板之间的动力学。在高浓度下,我们观察到共旋转和反旋转构型的环之间的耗尽式吸引力,导致二聚体的形成。值得注意的是,这种相互作用的范围可以扩展到几个颗粒直径,而被动系统的相互作用通常仅限于颗粒大小。更有趣的是,在低粒子浓度下,环在两种情况下都表现出相互排斥,我们将其归因于它们之间局部的高粒子浓度,这表明了一种与传统耗尽相互作用相反的机制。此外,我们还研究了二聚环的扩散特性,并将其与孤立环的扩散特性进行了比较。与单环相比,二聚体的角扩散明显受到抑制,但其平移扩散几乎保持不变。
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来源期刊
Soft Matter
Soft Matter 工程技术-材料科学:综合
CiteScore
6.00
自引率
5.90%
发文量
891
审稿时长
1.9 months
期刊介绍: Soft Matter is an international journal published by the Royal Society of Chemistry using Engineering-Materials Science: A Synthesis as its research focus. It publishes original research articles, review articles, and synthesis articles related to this field, reporting the latest discoveries in the relevant theoretical, practical, and applied disciplines in a timely manner, and aims to promote the rapid exchange of scientific information in this subject area. The journal is an open access journal. The journal is an open access journal and has not been placed on the alert list in the last three years.
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