Laura E. English, Ross A. Jackson, Nicholas J. Evans, Dawid J. Babula, Harvey J. Draper, Sarah R. Brown, Joseph Fletcher, David J. Liptrot and Kyle G. Pearce
{"title":"Mechanochemically micronised Na/NaCl; a superfine reductant†","authors":"Laura E. English, Ross A. Jackson, Nicholas J. Evans, Dawid J. Babula, Harvey J. Draper, Sarah R. Brown, Joseph Fletcher, David J. Liptrot and Kyle G. Pearce","doi":"10.1039/D5MR00039D","DOIUrl":null,"url":null,"abstract":"<p >A free-flowing, homogeneous and non-pyrophoric powder of Na/NaCl is prepared <em>via</em> planetary ball-milling. The mechanochemically micronised Na/NaCl serves as a highly activated source of sodium and was used to prepare [(<small><sup>Ar</sup></small>BDI)Mg]<small><sub>2</sub></small> (BDI = HC{(Me)CNAr}<small><sub>2</sub></small>; Ar = Dipp, 2,6-<em>i</em>-Pr<small><sub>2</sub></small>C<small><sub>6</sub></small>H<small><sub>3</sub></small>; Mes, 2,4,6-CH<small><sub>3</sub></small>C<small><sub>6</sub></small>H<small><sub>2</sub></small>) <em>via</em> ball milling in 75 and 45 minutes, respectively.</p>","PeriodicalId":101140,"journal":{"name":"RSC Mechanochemistry","volume":" 4","pages":" 503-506"},"PeriodicalIF":0.0000,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/mr/d5mr00039d?page=search","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"RSC Mechanochemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/mr/d5mr00039d","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A free-flowing, homogeneous and non-pyrophoric powder of Na/NaCl is prepared via planetary ball-milling. The mechanochemically micronised Na/NaCl serves as a highly activated source of sodium and was used to prepare [(ArBDI)Mg]2 (BDI = HC{(Me)CNAr}2; Ar = Dipp, 2,6-i-Pr2C6H3; Mes, 2,4,6-CH3C6H2) via ball milling in 75 and 45 minutes, respectively.
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