Impact of GO and ITO nanostructures’ performance on the nanostructure and optical behavior of a newly fabricated blended-PPY conductive polymer for antibacterial applications

Abstract

Hybrid nanomaterials are attracting growing attention for their ability to improve the functional performance of polymer-based systems, making them strong contenders for advanced applications in the electronics and biomedical fields. In this study, novel hybrid nanocomposites were developed based on a polyvinylpyrrolidone (PVP) K30 matrix blended with the conductive polymer polypyrrole (PPy) and reinforced with graphene oxide (GO) and indium tin oxide (ITO) nanoparticles. The nanocomposites were fabricated using a solution-casting technique, with improved dispersion achieved through mechanical stirring and ultrasonication. Field emission scanning electron microscope (FESEM) images revealed a smooth surface morphology and an homogeneous distribution of nanomaterials within the polymer matrix. Meanwhile, Fourier transform infrared spectroscopy (FTIR) indicated strong physical interactions between the composite components, with X-ray diffraction confirming the semicrystalline behavior of PVP, which was strongly impacted by the contribution of the nanomaterials. UV–Vis spectroscopy showed significantly enhanced optical behavior, with a notable reduction in the optical band gap from ∼3.43 to 1.63 eV, indicating improved electronic transition efficiency. Furthermore, the well-dried solid films exhibited superior antibacterial activity, with inhibition zones increasing by 53.8% against Staphylococcus aureus and 46.1% against Escherichia coli. These findings highlight the novelty and multifunctionality of the developed nanocomposites, demonstrating their strong potential for use in flexible optical-electronics devices, antibacterial coatings, tissue engineering, and sensor applications and addressing current societal needs in the health, environmental, and medical sectors.