Continuous-flow electrochemical benzylic dehydrogenation of arylalkanes to arylalkenes†

IF 9.2 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Pub Date : 2025-05-22 DOI:10.1039/d5gc01442e

Xuan-Xuan Du , Shu-Fan He , Daixi Li , Yong Jiang , Chen Zhu , Tao Shen

引用次数: 0

Abstract

A novel acid-mediated continuous-flow electrochemical strategy for arylalkane dehydrogenation was described. This oxidant- and hydrogen acceptor-free protocol proceeds in a single step under mild conditions, affording a broad range of arylalkenes as single regioisomers in a short reaction time, providing a direct, scalable, and practical method for the synthesis of arylalkenes.

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芳基烷烃连续流电化学苯脱氢制芳基烯烃

介绍了一种新的酸介导的芳烷连续流电化学脱氢策略。这种无氧化剂和无氢受体的方案在温和的条件下一步进行，在短的反应时间内提供广泛的芳烯作为单区域异构体，为芳烯的合成提供了一种直接，可扩展和实用的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Green Chemistry 化学-化学综合

CiteScore

16.10

自引率

7.10%

发文量

677

审稿时长

1.4 months

期刊介绍： Green Chemistry is a journal that provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998), which defines green chemistry as the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry aims to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. The journal welcomes submissions on all aspects of research relating to this endeavor and publishes original and significant cutting-edge research that is likely to be of wide general appeal. For a work to be published, it must present a significant advance in green chemistry, including a comparison with existing methods and a demonstration of advantages over those methods.