Covalent and non-covalent carbon nanotube functionalization: A review for the case of assessment criteria, and practical implementation in wastewater treatment
Mayowa Ezekiel Oladipo , Samuel Sunday Ogunsola , Peter Olusakin Oladoye
{"title":"Covalent and non-covalent carbon nanotube functionalization: A review for the case of assessment criteria, and practical implementation in wastewater treatment","authors":"Mayowa Ezekiel Oladipo , Samuel Sunday Ogunsola , Peter Olusakin Oladoye","doi":"10.1016/j.chemosphere.2025.144549","DOIUrl":null,"url":null,"abstract":"<div><div>The rising occurrence of complex and persistent pollutants in aquatic ecosystems has resulted in an increased demand for advanced treatment materials, positioning carbon nanotubes (CNTs) as a highly promising option for wastewater treatment. Owing to their remarkable adsorption properties, structural flexibility, and versatility when compared to conventional materials, research on CNTs is both vital and necessary for the advancement of next-generation water purification technologies. This study presents a comprehensive review of the current literature concerning the adsorption properties of CNTs, systematically evaluating various functionalization methods that enhance the solubility and dispersion of CNTs in aqueous environments, as well as the ways in which these modifications improve adsorption of pollutants. This review specifically emphasizes the comparative benefits and drawbacks of covalent and non-covalent functionalization methods based on assessment criteria, practical application, and feasibility, providing valuable insights into their real-world applications and future potential, ultimately guiding the selection and development of optimized CNT-based systems for effective wastewater treatment.</div></div>","PeriodicalId":276,"journal":{"name":"Chemosphere","volume":"385 ","pages":"Article 144549"},"PeriodicalIF":8.1000,"publicationDate":"2025-06-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemosphere","FirstCategoryId":"93","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S004565352500493X","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENVIRONMENTAL SCIENCES","Score":null,"Total":0}
引用次数: 0
Abstract
The rising occurrence of complex and persistent pollutants in aquatic ecosystems has resulted in an increased demand for advanced treatment materials, positioning carbon nanotubes (CNTs) as a highly promising option for wastewater treatment. Owing to their remarkable adsorption properties, structural flexibility, and versatility when compared to conventional materials, research on CNTs is both vital and necessary for the advancement of next-generation water purification technologies. This study presents a comprehensive review of the current literature concerning the adsorption properties of CNTs, systematically evaluating various functionalization methods that enhance the solubility and dispersion of CNTs in aqueous environments, as well as the ways in which these modifications improve adsorption of pollutants. This review specifically emphasizes the comparative benefits and drawbacks of covalent and non-covalent functionalization methods based on assessment criteria, practical application, and feasibility, providing valuable insights into their real-world applications and future potential, ultimately guiding the selection and development of optimized CNT-based systems for effective wastewater treatment.
期刊介绍:
Chemosphere, being an international multidisciplinary journal, is dedicated to publishing original communications and review articles on chemicals in the environment. The scope covers a wide range of topics, including the identification, quantification, behavior, fate, toxicology, treatment, and remediation of chemicals in the bio-, hydro-, litho-, and atmosphere, ensuring the broad dissemination of research in this field.