Mechanical and Morphological Properties of Uniaxially Oriented and Heat-Treated Poly(Lactic Acid)/Poly(Butylene Adipate-Co-Terephthalate) Blends

IF 2 4区 工程技术 Q3 ENGINEERING, CHEMICAL
Gergely Csézi, Tamás Tábi
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引用次数: 0

Abstract

This paper investigates the effect of poly(butylene adipate-co-terephthalate) (PBAT) on the mechanical and morphological properties of poly(lactic acid) (PLA) when the PLA is blended with 10%, 20%, and 30% PBAT and subjected to different draw ratios (DRs), followed by annealing at a fixed length. Results indicate that PBAT functions more as a strengthening agent than a toughening agent when the blend is drawn. Furthermore, both undrawn and most drawn samples exhibit higher crystallinity and lower cold crystallization temperatures (Tcc) (in proportion to PBAT ratio) compared to the unblended material, with crystallinity equilibrating at the highest measured draw ratio (DR) of 4, as determined by differential scanning calorimetry (DSC). The crystallinity of the annealed samples equilibrates at 45%–47%, demonstrating the effectiveness of heat treatment at the cold crystallization temperatures of the samples, as measured by DSC, which decreases with increasing DR. However, X-ray diffraction (XRD) results show that heat treatment at the original Tcc, specific to the undrawn PLA, results in higher crystal orientation.

Abstract Image

单轴取向和热处理的聚乳酸/聚己二酸丁二酯共混物的力学和形态性能
本文研究了聚己二酸丁二酯(PBAT)对聚乳酸(PLA)力学性能和形态性能的影响,当PLA与10%、20%和30% PBAT共混,进行不同拉伸比(DRs),然后在固定长度下退火。结果表明,在共混拉伸过程中,PBAT的强化作用大于增韧作用。此外,与未混合的材料相比,未拉伸和大部分拉伸的样品都表现出更高的结晶度和更低的冷结晶温度(Tcc)(与PBAT比例成比例),结晶度在最高测量拉伸比(DR)为4时达到平衡,这是通过差示扫描量热法(DSC)确定的。退火后样品的结晶度在45% ~ 47%之间达到平衡,DSC测量表明,在样品的冷结晶温度下热处理的有效性,随着dr的增加而降低。然而,x射线衍射(XRD)结果表明,针对未拉伸的PLA,在原始Tcc下热处理会导致更高的晶体取向。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Advances in Polymer Technology
Advances in Polymer Technology 工程技术-高分子科学
CiteScore
5.50
自引率
0.00%
发文量
70
审稿时长
9 months
期刊介绍: Advances in Polymer Technology publishes articles reporting important developments in polymeric materials, their manufacture and processing, and polymer product design, as well as those considering the economic and environmental impacts of polymer technology. The journal primarily caters to researchers, technologists, engineers, consultants, and production personnel.
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