{"title":"Surface stabilized porous cobalt polyphthalocyanine with enhanced reversibility for durable lithium storage","authors":"Zaoyan Yu, Wenruo Li, Luzheng Zhao, Jiancong Guo, Haoyuan Zhu, Yushuai Song, Xu Han, Zhongsheng Wen","doi":"10.1016/j.jpcs.2025.112980","DOIUrl":null,"url":null,"abstract":"<div><div>Cobalt polyphthalocyanines (CoPPcs) are a potential organic anode material for lithium-ion batteries (LIBs) for their tunable microstructure and environmental friendliness. However, its naturally highly compact stacking structure hinders the kinetics of lithium-ion diffusion, and its unstable chemical property deteriorates the surface and structural stabilization. A strategy of incorporating the coordination reaction and the exfoliation process is proposed to configure lamellar porous CoPPcs with stabilized surface/structure. An organophosphate compound of trioctylphosphine oxide (TOPO) is strategically introduced in the preparation of CoPPc to achieve the target. The study demonstrates that the optimized porous CoPPc with less stacking structure exhibits enhanced reversible capacity retention of 854.9 mAh g<sup>−1</sup> after 500 cycles at 200 mA g<sup>−1</sup>, showing excellent electrochemical stability prior to the previously reported results. In addition, the designed CoPPc maintains an amazing high capacity of 963.6 mAh g<sup>−1</sup> after 1000 cycles even at a relatively high current density of 1 A g<sup>−1</sup>, presenting a high endurability for rapid charging-discharging process. This work provides a new avenue to rationally modify and stabilize the structure for high-performance organic anodes for LIBs.</div></div>","PeriodicalId":16811,"journal":{"name":"Journal of Physics and Chemistry of Solids","volume":"207 ","pages":"Article 112980"},"PeriodicalIF":4.3000,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physics and Chemistry of Solids","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0022369725004329","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Cobalt polyphthalocyanines (CoPPcs) are a potential organic anode material for lithium-ion batteries (LIBs) for their tunable microstructure and environmental friendliness. However, its naturally highly compact stacking structure hinders the kinetics of lithium-ion diffusion, and its unstable chemical property deteriorates the surface and structural stabilization. A strategy of incorporating the coordination reaction and the exfoliation process is proposed to configure lamellar porous CoPPcs with stabilized surface/structure. An organophosphate compound of trioctylphosphine oxide (TOPO) is strategically introduced in the preparation of CoPPc to achieve the target. The study demonstrates that the optimized porous CoPPc with less stacking structure exhibits enhanced reversible capacity retention of 854.9 mAh g−1 after 500 cycles at 200 mA g−1, showing excellent electrochemical stability prior to the previously reported results. In addition, the designed CoPPc maintains an amazing high capacity of 963.6 mAh g−1 after 1000 cycles even at a relatively high current density of 1 A g−1, presenting a high endurability for rapid charging-discharging process. This work provides a new avenue to rationally modify and stabilize the structure for high-performance organic anodes for LIBs.
聚酞菁钴(CoPPcs)具有微观结构可调和环境友好性,是锂离子电池(LIBs)极具潜力的有机负极材料。然而,其天然的高度致密的堆积结构阻碍了锂离子的扩散动力学,其不稳定的化学性质恶化了表面和结构的稳定性。提出了一种结合配位反应和剥离过程的策略来配置具有稳定表面结构的层状多孔CoPPcs。为了实现这一目标,在制备CoPPc过程中战略性地引入了氧化三辛基膦(TOPO)有机磷酸盐化合物。研究表明,优化后的多孔CoPPc具有较少的堆叠结构,在200 mA g - 1下循环500次后,其可逆容量保持在854.9 mAh g - 1,比之前报道的结果显示出优异的电化学稳定性。此外,所设计的CoPPc即使在较高的电流密度为1 a g−1的情况下,也能在1000次循环后保持963.6 mAh g−1的高容量,具有很高的快速充放电耐久性。这项工作为合理修饰和稳定高性能有机锂阳极结构提供了新的途径。
期刊介绍:
The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems.
Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal:
Low-dimensional systems
Exotic states of quantum electron matter including topological phases
Energy conversion and storage
Interfaces, nanoparticles and catalysts.