A Pair of Giant Mo Blue Wheels: {Mo80} Monomer and {Mo160} Dimer for Efficient Conversion From Light‐Dominated All‐Weather Environmental Energy to Electricity

IF 18.5 1区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Mingjun Hou, Xingwang Li, Congcong Zhao, Weichao Chen, Kuizhan Shao, Weilin Chen, Chao Qin, Xinlong Wang, Zhongmin Su
{"title":"A Pair of Giant Mo Blue Wheels: {Mo80} Monomer and {Mo160} Dimer for Efficient Conversion From Light‐Dominated All‐Weather Environmental Energy to Electricity","authors":"Mingjun Hou, Xingwang Li, Congcong Zhao, Weichao Chen, Kuizhan Shao, Weilin Chen, Chao Qin, Xinlong Wang, Zhongmin Su","doi":"10.1002/adfm.202510454","DOIUrl":null,"url":null,"abstract":"Molybdenum blue (MB) clusters show promise for light‐dominated low‐value energy harvesting due to their broad‐spectrum absorption, tunable redox activity, and chemical stability. However, it is not available to date. Herein, a new type of MB wheels Mo<jats:sub>160</jats:sub> dimer and the precise synthesis of its monomer analogs Mo<jats:sub>80</jats:sub> is reported through an amino acid‐mediated assembly strategy. The half‐closed octameric frameworks featuring compressed wheels are orderly constructed by two {Mo<jats:sub>9/10</jats:sub>} and six classical {Mo<jats:sub>9</jats:sub>} building blocks as well as central {Mo<jats:sub>3</jats:sub>} or {Mo<jats:sub>8</jats:sub>} caps. Such structural analogs enable multifunctional light‐dominated energy conversion molecular‐based devices. Mo<jats:sub>160</jats:sub>/ethyl cellulose film delivers 430.8 µA photocurrent and 147.7 µV photovoltage under AM 1.5G light. When powered by simulated all‐weather environment combining light, wind, and rain energy, Mo<jats:sub>160</jats:sub> film achieves an ideal output power density of ≈0.11 mW m<jats:sup>−2</jats:sup> at low impedance (≈10 Ω) with long‐term durability, which is 2.58 times higher than that of Mo<jats:sub>80</jats:sub> film and even tens of times better than other types of polyoxometalate film. Theoretical investigations focusing on the electronic characteristics of key building blocks in MB clusters have elucidated molecular‐level structure‐property relationships. This work advances the controlled synthesis of giant polyoxometalates and their implementation in light‐dominated low‐value energy conversion technologies.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":"17 1","pages":""},"PeriodicalIF":18.5000,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202510454","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Molybdenum blue (MB) clusters show promise for light‐dominated low‐value energy harvesting due to their broad‐spectrum absorption, tunable redox activity, and chemical stability. However, it is not available to date. Herein, a new type of MB wheels Mo160 dimer and the precise synthesis of its monomer analogs Mo80 is reported through an amino acid‐mediated assembly strategy. The half‐closed octameric frameworks featuring compressed wheels are orderly constructed by two {Mo9/10} and six classical {Mo9} building blocks as well as central {Mo3} or {Mo8} caps. Such structural analogs enable multifunctional light‐dominated energy conversion molecular‐based devices. Mo160/ethyl cellulose film delivers 430.8 µA photocurrent and 147.7 µV photovoltage under AM 1.5G light. When powered by simulated all‐weather environment combining light, wind, and rain energy, Mo160 film achieves an ideal output power density of ≈0.11 mW m−2 at low impedance (≈10 Ω) with long‐term durability, which is 2.58 times higher than that of Mo80 film and even tens of times better than other types of polyoxometalate film. Theoretical investigations focusing on the electronic characteristics of key building blocks in MB clusters have elucidated molecular‐level structure‐property relationships. This work advances the controlled synthesis of giant polyoxometalates and their implementation in light‐dominated low‐value energy conversion technologies.
一对巨大的Mo蓝轮:{Mo80}单体和{Mo160}二聚体用于光主导的全天候环境能源到电能的高效转换
钼蓝(MB)簇由于其广谱吸收、可调节的氧化还原活性和化学稳定性,在光主导的低价值能量收集中显示出前景。然而,它是不可用的日期。本文报道了一种新型MB车轮Mo160二聚体及其单体类似物Mo80的氨基酸介导组装策略的精确合成。具有压缩轮的半封闭八元框架由两个{Mo9/10}和六个经典{Mo9}构建块以及中心{Mo3}或{Mo8}帽有序构建。这种结构类似物使得基于分子的多功能光主导能量转换器件成为可能。Mo160/乙基纤维素薄膜在AM 1.5G光下提供430.8µA光电流和147.7µV光电压。在光、风、雨模拟全天候环境下供电时,Mo160薄膜在低阻抗下的理想输出功率密度为≈0.11 mW m−2(≈10 Ω),具有长期耐用性,比Mo80薄膜高2.58倍,甚至比其他类型的多金属氧酸盐薄膜好几十倍。理论研究聚焦于MB簇中关键构建块的电子特性,阐明了分子水平的结构-性质关系。这项工作推进了巨型多金属氧酸盐的受控合成及其在光主导的低价值能量转换技术中的实现。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 求助全文
来源期刊
Advanced Functional Materials
Advanced Functional Materials 工程技术-材料科学:综合
CiteScore
29.50
自引率
4.20%
发文量
2086
审稿时长
2.1 months
期刊介绍: Firmly established as a top-tier materials science journal, Advanced Functional Materials reports breakthrough research in all aspects of materials science, including nanotechnology, chemistry, physics, and biology every week. Advanced Functional Materials is known for its rapid and fair peer review, quality content, and high impact, making it the first choice of the international materials science community.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信