Demid S. Abramkin , Ivan A. Aleksandrov , Victor V. Atuchin
{"title":"Prospects of using self-assembled GaN/AlN quantum dots for universal memory elements","authors":"Demid S. Abramkin , Ivan A. Aleksandrov , Victor V. Atuchin","doi":"10.1016/j.jpcs.2025.112945","DOIUrl":null,"url":null,"abstract":"<div><div>The possibility of using self-assembled GaN/AlN quantum dots (SAQDs) for universal memory elements is considered. The energy spectrum of GaN/AlN SAQDs was calculated to reveal the dependence of the electron localization energy (<em>E</em><sub>loc</sub>) on their sizes and elastic deformation. The calculations took into account the effects of strain, spontaneous and piezo-polarization and the quantum confinement effect. The energy spectrum calculations were performed in the 8-band k × p approach. The vertical and longitudinal sizes of the SAQDs were varied over a wide range. To verify the calculations, the calculated SAQDs optical transition energy was compared with the photoluminescence data and information on the SAQDs sizes available in the literature. It was shown that the pseudomorphically strained SAQDs with height >2–3.5 nm (depending on the aspect ratio) are characterized by the electron localization energy value of more than 1.5 eV. According to the literature data, the formation of pseudomorphically strained SAQDs with these sizes is possible, and it makes GaN/AlN SAQDs promising for the fabrication of memory devices with a charge storage time of more than 10 years.</div></div>","PeriodicalId":16811,"journal":{"name":"Journal of Physics and Chemistry of Solids","volume":"207 ","pages":"Article 112945"},"PeriodicalIF":4.3000,"publicationDate":"2025-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physics and Chemistry of Solids","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S002236972500397X","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The possibility of using self-assembled GaN/AlN quantum dots (SAQDs) for universal memory elements is considered. The energy spectrum of GaN/AlN SAQDs was calculated to reveal the dependence of the electron localization energy (Eloc) on their sizes and elastic deformation. The calculations took into account the effects of strain, spontaneous and piezo-polarization and the quantum confinement effect. The energy spectrum calculations were performed in the 8-band k × p approach. The vertical and longitudinal sizes of the SAQDs were varied over a wide range. To verify the calculations, the calculated SAQDs optical transition energy was compared with the photoluminescence data and information on the SAQDs sizes available in the literature. It was shown that the pseudomorphically strained SAQDs with height >2–3.5 nm (depending on the aspect ratio) are characterized by the electron localization energy value of more than 1.5 eV. According to the literature data, the formation of pseudomorphically strained SAQDs with these sizes is possible, and it makes GaN/AlN SAQDs promising for the fabrication of memory devices with a charge storage time of more than 10 years.
期刊介绍:
The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems.
Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal:
Low-dimensional systems
Exotic states of quantum electron matter including topological phases
Energy conversion and storage
Interfaces, nanoparticles and catalysts.