A Recyclable, Adhesive, and Self-Healing Ionogel Based on Zinc-Halogen Coordination Anion Crosslinked Poly(ionic Liquid)/Ionic Liquid Networks for High-Performance Microwave Absorption.

IF 5 3区 化学 Q1 POLYMER SCIENCE
Gels Pub Date : 2025-06-05 DOI:10.3390/gels11060436
Lei Wang, Jie Liu, Meng Zong, Yi Liu, Jianfeng Zhu
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引用次数: 0

Abstract

In the past, powder-like microwave absorbers have made notable breakthroughs in performance enhancements, but complicated processes and undesirable properties have limited their practical application. Herein, a novel poly(ionic liquid) (PIL)-based ionic gel with excellent microwave absorption properties was prepared via a facile UV-initiated polymerization method. By simply adjusting the mole ratio of the polymerizable ionic liquid (IL)monomer and the IL dispersion medium, the microwave absorption properties of the obtained ionic gels can be tuned. A maximum reflection loss (RLmax) of -45.7 dB and an effective absorption bandwidth (EAB) of 8.08 GHz were achieved, which was mainly ascribed to high ionic conduction loss induced by the high content of the dispersion medium. Furthermore, it displayed recyclable, adhesive, and self-healing properties, thus providing a new candidate for developing efficient microwave absorbers for practical applications.

基于锌-卤素配位阴离子交联聚(离子液体)/离子液体网络的可回收、可粘接、自修复离子凝胶用于高性能微波吸收。
过去,粉末状微波吸收剂在性能增强方面取得了显著的突破,但复杂的工艺和不良的性能限制了它们的实际应用。本文采用紫外引发聚合法制备了一种新型的具有优异微波吸收性能的聚离子液体离子凝胶。通过简单地调整可聚合离子液体(IL)单体和IL分散介质的摩尔比,可以调节离子凝胶的微波吸收性能。最大反射损耗(RLmax)为-45.7 dB,有效吸收带宽(EAB)为8.08 GHz,这主要是由于高色散介质含量导致的高离子传导损耗所致。此外,它还具有可回收、粘接和自修复的特性,从而为开发实际应用的高效微波吸收剂提供了新的候选材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Gels
Gels POLYMER SCIENCE-
CiteScore
4.70
自引率
19.60%
发文量
707
审稿时长
11 weeks
期刊介绍: The journal Gels (ISSN 2310-2861) is an international, open access journal on physical (supramolecular) and chemical gel-based materials. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the maximum length of the papers, and full experimental details must be provided so that the results can be reproduced. Short communications, full research papers and review papers are accepted formats for the preparation of the manuscripts. Gels aims to serve as a reference journal with a focus on gel materials for researchers working in both academia and industry. Therefore, papers demonstrating practical applications of these materials are particularly welcome. Occasionally, invited contributions (i.e., original research and review articles) on emerging issues and high-tech applications of gels are published as special issues.
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