Cover Picture: α-Azaaryl Carbonyl Derivatives in Stereodivergent Catalytic Reactions (BKCS 6/2025) Ilwoo Song, Byungjun Kim, Hooseung Lee, Sarah Yunmi Lee

IF 1.7 4区化学

Bulletin of the Korean Chemical Society Pub Date : 2025-06-25 DOI:10.1002/bkcs.12866

引用次数: 0

Abstract

The cover image depicts a Goldberg machine symbolizing the stereodivergent reaction of α-azaaryl carbonyl derivatives with electrophilic partners (E⁺), producing azaarenes with multiple stereocenters (R,S). By combining a chiral copper Lewis acid with a second chiral catalyst (Ir, Pd, Ni, Ru, or amines) and tuning the stereochemical environment, all possible stereoisomers can be selectively accessed. Details are in the article by Ilwoo Song, Byungjun Kim, Hooseung Lee, and Sarah Yunmi Lee.

Abstract Image

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封面图：立体发散催化反应中的α-氮杂基羰基衍生物(BKCS 6/2025

封面图描绘了一个Goldberg机，表示α-氮扎芳羰基衍生物与亲电伴侣（E⁺）的立体发散反应，生成具有多个立体中心的氮扎芳烯（R，S）。通过手性铜刘易斯酸与第二手性催化剂（Ir, Pd, Ni， Ru或胺）结合并调整立体化学环境，可以选择性地获得所有可能的立体异构体。详细内容请参见宋一宇、金秉俊、李侯升、李允美等人的文章。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Bulletin of the Korean Chemical Society Chemistry-General Chemistry

自引率

23.50%

发文量

182

期刊介绍： The Bulletin of the Korean Chemical Society is an official research journal of the Korean Chemical Society. It was founded in 1980 and reaches out to the chemical community worldwide. It is strictly peer-reviewed and welcomes Accounts, Communications, Articles, and Notes written in English. The scope of the journal covers all major areas of chemistry: analytical chemistry, electrochemistry, industrial chemistry, inorganic chemistry, life-science chemistry, macromolecular chemistry, organic synthesis, non-synthetic organic chemistry, physical chemistry, and materials chemistry.