Recent progress in electrochemical synthesis of hypochlorite and its future outlook

IF 6.4 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Liuyu Ji, Junyang Ding, Caiyun Wang, Yang Luo, Qian Liu, Guangzhi Hu and Xijun Liu
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Abstract

Disinfection plays a critical role in ensuring the safety of drinking water during treatment. Sodium hypochlorite disinfection, a method that has been demonstrated to be both cost-effective and safe, exhibits considerable promise for widespread implementation when compared to alternative methods. Electrochemical synthesis of sodium hypochlorite solution has emerged as a preferred alternative to traditional chemical methods due to its numerous advantages, including high current efficiency, low energy consumption, ease of operation, accessible raw materials, high purity, and controllable safety. Nevertheless, the instability of the reaction in the electrochemical synthesis process poses a significant challenge to its broader implementation. This study explores the underlying principles of electrochemical synthesis for sodium hypochlorite solution and investigates the impact of various conditions on electrolysis efficiency. The objective of this study is to ascertain the most optimal electrolysis conditions. The study also examines various electrode materials for the anode and cathode, and it summarizes typical strategies for enhancing electrode performance. Furthermore, the study investigates the factors influencing the stability of sodium hypochlorite solution to enable precise regulation of its efficacy, thereby promoting the advancement of electrochemical synthesis technology for sodium hypochlorite solution.

Abstract Image

电化学合成次氯酸盐的研究进展及前景展望
在处理过程中,消毒对确保饮用水安全起着至关重要的作用。次氯酸钠消毒是一种已被证明既具有成本效益又安全的方法,与其他方法相比,具有广泛实施的巨大希望。电化学合成次氯酸钠溶液具有电流效率高、能耗低、操作方便、原料可及、纯度高、安全可控等优点,已成为传统化学方法的首选替代方法。然而,电化学合成过程中反应的不稳定性对其广泛应用提出了重大挑战。本研究探讨了电化学合成次氯酸钠溶液的基本原理,并考察了不同条件对电解效率的影响。本研究的目的是确定最佳的电解条件。研究还考察了各种阳极和阴极电极材料,并总结了提高电极性能的典型策略。进一步研究影响次氯酸钠溶液稳定性的因素,实现对其药效的精准调控,从而推动次氯酸钠溶液电化学合成技术的进步。
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来源期刊
Materials Chemistry Frontiers
Materials Chemistry Frontiers Materials Science-Materials Chemistry
CiteScore
12.00
自引率
2.90%
发文量
313
期刊介绍: Materials Chemistry Frontiers focuses on the synthesis and chemistry of exciting new materials, and the development of improved fabrication techniques. Characterisation and fundamental studies that are of broad appeal are also welcome. This is the ideal home for studies of a significant nature that further the development of organic, inorganic, composite and nano-materials.
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