Research progress of catalysts for synthesis of glycerol carbonate form glycerol and urea

Q3 Energy

燃料化学学报 Pub Date : 2025-06-01 DOI:10.1016/S1872-5813(25)60538-X

Yuhua WANG , Hongguang LI , Liang DING , Yongli KOU , Wenbo QI , Ning ZHAO

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引用次数: 0

Abstract

Transformation of urea and glycerol to glycerol carbonate is an environmental friendly and economical process. Catalysts play an indispensable role in the process. Although many catalysts have been developed, the performance of the catalysts still cannot meet the needs of industrialization. In this paper, research progress of the homogeneous and heterogeneous catalysts of the reaction over the past 20 years were reviewed systematically. According to the types and active centers of catalysts, the catalysts were classified systematically and analyzed in detail. The typical reaction mechanisms were also summarized. The research and development direction of catalysts is made more explicit through systematic classification and mechanism analysis. The article reveals more novel catalysts have been designed and used for the reaction, such as mixed metal oxides with special structures, solid wastes and non-metallic materials. This work summarized the current state of research and prospected possible routes for design of novel catalysts. It is hoped that this review can provide some references for developing efficient catalysts.

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甘油和尿素合成碳酸甘油催化剂的研究进展

尿素和甘油转化为碳酸甘油是一种环保、经济的工艺。催化剂在这一过程中起着不可或缺的作用。虽然已经开发了许多催化剂，但催化剂的性能仍不能满足工业化的需要。本文系统地综述了近20年来该反应的均相和非均相催化剂的研究进展。根据催化剂的种类和活性中心，对催化剂进行了系统的分类和详细的分析。总结了典型的反应机理。通过系统的分类和机理分析，明确了催化剂的研究和发展方向。本文揭示了更多新型催化剂的设计和应用，如特殊结构的混合金属氧化物、固体废物和非金属材料。本文总结了目前的研究现状，展望了新型催化剂设计的可能途径。希望能对高效催化剂的开发提供一定的参考。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

燃料化学学报 Chemical Engineering-Chemical Engineering (all)

CiteScore

2.80

自引率

0.00%

发文量

5825

期刊介绍： Journal of Fuel Chemistry and Technology (Ranliao Huaxue Xuebao) is a Chinese Academy of Sciences(CAS) journal started in 1956, sponsored by the Chinese Chemical Society and the Institute of Coal Chemistry, Chinese Academy of Sciences(CAS). The journal is published bimonthly by Science Press in China and widely distributed in about 20 countries. Journal of Fuel Chemistry and Technology publishes reports of both basic and applied research in the chemistry and chemical engineering of many energy sources, including that involved in the nature, processing and utilization of coal, petroleum, oil shale, natural gas, biomass and synfuels, as well as related subjects of increasing interest such as C1 chemistry, pollutions control and new catalytic materials. Types of publications include original research articles, short communications, research notes and reviews. Both domestic and international contributors are welcome. Manuscripts written in Chinese or English will be accepted. Additional English titles, abstracts and key words should be included in Chinese manuscripts. All manuscripts are subject to critical review by the editorial committee, which is composed of about 10 foreign and 50 Chinese experts in fuel science. Journal of Fuel Chemistry and Technology has been a source of primary research work in fuel chemistry as a Chinese core scientific periodical.