{"title":"Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysi.","authors":"Jiasi Li,Shik Chi Edman Tsang,Guangchao Li","doi":"10.1002/adma.202502101","DOIUrl":null,"url":null,"abstract":"Frustrated Lewis pair (FLP) in heterogeneous chemistry have garnered tremendous attention in recent years owing to their diverse structural designs and outstanding activation ability for small molecules. The ability to tailor the structure of FLP enables precise control over their reactivity and selectivity, paving the way for the creation of catalysts for specific reactions. This review offers an in-depth examination of the design, characterization, and application of FLP within heterogeneous systems over the past few years. The current challenges in developing solid FLP catalysts are discussed. Furthermore, future potential advancements are explored, considering how emerging technologies and innovative approaches could enhance the design, advance characterization, and application of FLP in heterogeneous chemistry. Through this detailed overview, it is aimed to provide valuable insights into the evolving landscape of FLP research and its implications for the future applications in catalysis.","PeriodicalId":114,"journal":{"name":"Advanced Materials","volume":"45 1","pages":"e2502101"},"PeriodicalIF":27.4000,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adma.202502101","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Frustrated Lewis pair (FLP) in heterogeneous chemistry have garnered tremendous attention in recent years owing to their diverse structural designs and outstanding activation ability for small molecules. The ability to tailor the structure of FLP enables precise control over their reactivity and selectivity, paving the way for the creation of catalysts for specific reactions. This review offers an in-depth examination of the design, characterization, and application of FLP within heterogeneous systems over the past few years. The current challenges in developing solid FLP catalysts are discussed. Furthermore, future potential advancements are explored, considering how emerging technologies and innovative approaches could enhance the design, advance characterization, and application of FLP in heterogeneous chemistry. Through this detailed overview, it is aimed to provide valuable insights into the evolving landscape of FLP research and its implications for the future applications in catalysis.
期刊介绍:
Advanced Materials, one of the world's most prestigious journals and the foundation of the Advanced portfolio, is the home of choice for best-in-class materials science for more than 30 years. Following this fast-growing and interdisciplinary field, we are considering and publishing the most important discoveries on any and all materials from materials scientists, chemists, physicists, engineers as well as health and life scientists and bringing you the latest results and trends in modern materials-related research every week.