The role of high recycled content and heat treatments on microstructure, mechanical properties, and sustainability for an AlSi10MnMg structural automotive component
{"title":"The role of high recycled content and heat treatments on microstructure, mechanical properties, and sustainability for an AlSi10MnMg structural automotive component","authors":"Riccardo Arcaleni , Luca Girelli , Lavinia Tonelli , Lucia Lattanzi , Marialaura Tocci , Alessandro Morri , Annalisa Pola , Lorella Ceschini","doi":"10.1016/j.susmat.2025.e01491","DOIUrl":null,"url":null,"abstract":"<div><div>Secondary aluminum alloys are produced with end-of-life scraps and are gaining importance for environmental sustainability, thanks to their low intrinsic carbon footprint and energy saving compared to the primary ones. They are increasingly used in the automotive sector for large and complex cast components. However, recycled alloys contaminants like Fe promote the formation of brittle intermetallic compounds, which negatively affect tensile strength and ductility. This study compares the mechanical performance and environmental impact of primary and recycled high pressure die casting AlSi10MnMg (EN AB 43500) alloy under as-produced and heat-treated conditions. Samples were extracted from a die-cast automotive component and subjected to annealing and an optimized T6 heat treatment to balance strength and ductility. Microstructural analysis using field emission scanning electron microscopy revealed a similar pores area fraction, as well as shape, size, and distribution of brittle acicular β-Al<sub>5</sub>FeSi and polygonal α-Al<sub>15</sub>(Fe,Mn)<sub>3</sub>Si<sub>2</sub> Fe-rich phases in the primary and recycled alloys under different heat treatment conditions. This similarity justifies the comparable mechanical behavior of the primary and recycled alloy, characterized by limited ductility in the as-produced condition, often insufficient for safety-critical structural components. Heat treatments significantly improved ductility, increasing it by 40–50 % after annealing and nearly doubling it after T6 due to the fragmentation, spheroidization, and coarsening of the eutectic Si. However, the microstructure change reduces strength by a third after annealing and by 20 % after T6, ultimately influencing the final fracture mechanisms. Moreover, heat treatments increase energy consumption, with annealing and T6 leading to about 25 % and 30 % rises, respectively, making them justified only for elongation enhancement.</div></div>","PeriodicalId":22097,"journal":{"name":"Sustainable Materials and Technologies","volume":"45 ","pages":"Article e01491"},"PeriodicalIF":9.2000,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Sustainable Materials and Technologies","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2214993725002593","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
引用次数: 0
Abstract
Secondary aluminum alloys are produced with end-of-life scraps and are gaining importance for environmental sustainability, thanks to their low intrinsic carbon footprint and energy saving compared to the primary ones. They are increasingly used in the automotive sector for large and complex cast components. However, recycled alloys contaminants like Fe promote the formation of brittle intermetallic compounds, which negatively affect tensile strength and ductility. This study compares the mechanical performance and environmental impact of primary and recycled high pressure die casting AlSi10MnMg (EN AB 43500) alloy under as-produced and heat-treated conditions. Samples were extracted from a die-cast automotive component and subjected to annealing and an optimized T6 heat treatment to balance strength and ductility. Microstructural analysis using field emission scanning electron microscopy revealed a similar pores area fraction, as well as shape, size, and distribution of brittle acicular β-Al5FeSi and polygonal α-Al15(Fe,Mn)3Si2 Fe-rich phases in the primary and recycled alloys under different heat treatment conditions. This similarity justifies the comparable mechanical behavior of the primary and recycled alloy, characterized by limited ductility in the as-produced condition, often insufficient for safety-critical structural components. Heat treatments significantly improved ductility, increasing it by 40–50 % after annealing and nearly doubling it after T6 due to the fragmentation, spheroidization, and coarsening of the eutectic Si. However, the microstructure change reduces strength by a third after annealing and by 20 % after T6, ultimately influencing the final fracture mechanisms. Moreover, heat treatments increase energy consumption, with annealing and T6 leading to about 25 % and 30 % rises, respectively, making them justified only for elongation enhancement.
期刊介绍:
Sustainable Materials and Technologies (SM&T), an international, cross-disciplinary, fully open access journal published by Elsevier, focuses on original full-length research articles and reviews. It covers applied or fundamental science of nano-, micro-, meso-, and macro-scale aspects of materials and technologies for sustainable development. SM&T gives special attention to contributions that bridge the knowledge gap between materials and system designs.