{"title":"Hardness gradient multilayer coating for enhancing tribological property of AISI 1045 steel","authors":"Haoran Dong , Jian Zhang , Hao Wang , Feng Tian , Qinqin Wei , Jianglin Qin , Guoqiang Luo , Qiang Shen","doi":"10.1016/j.surfcoat.2025.132405","DOIUrl":null,"url":null,"abstract":"<div><div>Specialized equipment vehicles typically operate in complex environments, resulting in wear and failure of the AISI 1045 mild steel rotary seal shaft of the chassis. Extending the life of a material by depositing a hard coating on its surface is an efficient method, and the matrix in the previous study was cemented carbide. However, there is a significant difference in physical properties between the soft AISI 1045 steel and the hard coating, resulting in poor mechanical and tribological property. In this study, we design and prepared CrN/TiAlN multilayer coatings with hardness gradient by arc ion plating to reduce the residual stress inside the coating and enhance the tribological property. The CrN/TiAlN multilayer coatings are composed of CrN layer, CrN/TiAlN alternating layer, and TiAlN layer, in which the coating interfaces are well bonded without obvious defects. The hardness and modulus of CrN/TiAlN multilayer coatings increase with the CrN transition layer thickness, and the coating with 3.53 μm thick CrN layer has the largest hardness of 39.86 GPa, modulus of 386.72 GPa, and binding force of 24.59 N, as well as the smallest residual stress of −449.6 ± 42.3 MPa. After a 10,000 km simulated vehicle driving test, the wear depth of AISI 1045 steel is greater than 70 μm, while the surface of CrN/TiAlN coating has no obvious wear marks. Gradient design reduces the difference in physical parameters between the coating and the substrate, and the thickness increase of the CrN transition layer reduces the influence of the substrate on the coating strength, which together reduces the residual stress of the coating, improves its bonding force, and enhance tribological property. This work provides important prospects for the application of rotating sealing components in vehicles and theoretical references for improving the wear resistance of sealing surfaces.</div></div>","PeriodicalId":22009,"journal":{"name":"Surface & Coatings Technology","volume":"512 ","pages":"Article 132405"},"PeriodicalIF":5.3000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface & Coatings Technology","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0257897225006796","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COATINGS & FILMS","Score":null,"Total":0}
引用次数: 0
Abstract
Specialized equipment vehicles typically operate in complex environments, resulting in wear and failure of the AISI 1045 mild steel rotary seal shaft of the chassis. Extending the life of a material by depositing a hard coating on its surface is an efficient method, and the matrix in the previous study was cemented carbide. However, there is a significant difference in physical properties between the soft AISI 1045 steel and the hard coating, resulting in poor mechanical and tribological property. In this study, we design and prepared CrN/TiAlN multilayer coatings with hardness gradient by arc ion plating to reduce the residual stress inside the coating and enhance the tribological property. The CrN/TiAlN multilayer coatings are composed of CrN layer, CrN/TiAlN alternating layer, and TiAlN layer, in which the coating interfaces are well bonded without obvious defects. The hardness and modulus of CrN/TiAlN multilayer coatings increase with the CrN transition layer thickness, and the coating with 3.53 μm thick CrN layer has the largest hardness of 39.86 GPa, modulus of 386.72 GPa, and binding force of 24.59 N, as well as the smallest residual stress of −449.6 ± 42.3 MPa. After a 10,000 km simulated vehicle driving test, the wear depth of AISI 1045 steel is greater than 70 μm, while the surface of CrN/TiAlN coating has no obvious wear marks. Gradient design reduces the difference in physical parameters between the coating and the substrate, and the thickness increase of the CrN transition layer reduces the influence of the substrate on the coating strength, which together reduces the residual stress of the coating, improves its bonding force, and enhance tribological property. This work provides important prospects for the application of rotating sealing components in vehicles and theoretical references for improving the wear resistance of sealing surfaces.
期刊介绍:
Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance:
A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting.
B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.