Hardness gradient multilayer coating for enhancing tribological property of AISI 1045 steel

IF 5.3 2区 材料科学 Q1 MATERIALS SCIENCE, COATINGS & FILMS
Haoran Dong , Jian Zhang , Hao Wang , Feng Tian , Qinqin Wei , Jianglin Qin , Guoqiang Luo , Qiang Shen
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Abstract

Specialized equipment vehicles typically operate in complex environments, resulting in wear and failure of the AISI 1045 mild steel rotary seal shaft of the chassis. Extending the life of a material by depositing a hard coating on its surface is an efficient method, and the matrix in the previous study was cemented carbide. However, there is a significant difference in physical properties between the soft AISI 1045 steel and the hard coating, resulting in poor mechanical and tribological property. In this study, we design and prepared CrN/TiAlN multilayer coatings with hardness gradient by arc ion plating to reduce the residual stress inside the coating and enhance the tribological property. The CrN/TiAlN multilayer coatings are composed of CrN layer, CrN/TiAlN alternating layer, and TiAlN layer, in which the coating interfaces are well bonded without obvious defects. The hardness and modulus of CrN/TiAlN multilayer coatings increase with the CrN transition layer thickness, and the coating with 3.53 μm thick CrN layer has the largest hardness of 39.86 GPa, modulus of 386.72 GPa, and binding force of 24.59 N, as well as the smallest residual stress of −449.6 ± 42.3 MPa. After a 10,000 km simulated vehicle driving test, the wear depth of AISI 1045 steel is greater than 70 μm, while the surface of CrN/TiAlN coating has no obvious wear marks. Gradient design reduces the difference in physical parameters between the coating and the substrate, and the thickness increase of the CrN transition layer reduces the influence of the substrate on the coating strength, which together reduces the residual stress of the coating, improves its bonding force, and enhance tribological property. This work provides important prospects for the application of rotating sealing components in vehicles and theoretical references for improving the wear resistance of sealing surfaces.
提高AISI 1045钢摩擦学性能的硬度梯度多层涂层
专用设备车辆通常在复杂的环境中运行,导致底盘AISI 1045低碳钢旋转密封轴的磨损和失效。通过在材料表面沉积硬质涂层来延长材料寿命是一种有效的方法,而之前研究的基体是硬质合金。然而,软质AISI 1045钢的物理性能与硬涂层之间存在显著差异,导致其机械性能和摩擦学性能较差。本研究采用电弧离子镀的方法,设计并制备了具有硬度梯度的CrN/TiAlN多层涂层,以降低涂层内部的残余应力,提高涂层的摩擦学性能。CrN/TiAlN多层涂层由CrN层、CrN/TiAlN交替层和TiAlN层组成,涂层界面结合良好,无明显缺陷。CrN/TiAlN多层涂层的硬度和模量随CrN过渡层厚度的增加而增加,厚度为3.53 μm的CrN涂层硬度最大,为39.86 GPa,模量为386.72 GPa,结合力为24.59 N,残余应力最小,为−449.6±42.3 MPa。经过1万km模拟车辆行驶试验,AISI 1045钢的磨损深度大于70 μm,而CrN/TiAlN涂层表面无明显磨损痕迹。梯度设计减小了涂层与基体之间物理参数的差异,CrN过渡层厚度的增加减小了基体对涂层强度的影响,共同降低了涂层的残余应力,提高了涂层的结合力,增强了摩擦学性能。该工作为旋转密封元件在车辆上的应用提供了重要的前景,并为提高密封面的耐磨性提供了理论参考。
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来源期刊
Surface & Coatings Technology
Surface & Coatings Technology 工程技术-材料科学:膜
CiteScore
10.00
自引率
11.10%
发文量
921
审稿时长
19 days
期刊介绍: Surface and Coatings Technology is an international archival journal publishing scientific papers on significant developments in surface and interface engineering to modify and improve the surface properties of materials for protection in demanding contact conditions or aggressive environments, or for enhanced functional performance. Contributions range from original scientific articles concerned with fundamental and applied aspects of research or direct applications of metallic, inorganic, organic and composite coatings, to invited reviews of current technology in specific areas. Papers submitted to this journal are expected to be in line with the following aspects in processes, and properties/performance: A. Processes: Physical and chemical vapour deposition techniques, thermal and plasma spraying, surface modification by directed energy techniques such as ion, electron and laser beams, thermo-chemical treatment, wet chemical and electrochemical processes such as plating, sol-gel coating, anodization, plasma electrolytic oxidation, etc., but excluding painting. B. Properties/performance: friction performance, wear resistance (e.g., abrasion, erosion, fretting, etc), corrosion and oxidation resistance, thermal protection, diffusion resistance, hydrophilicity/hydrophobicity, and properties relevant to smart materials behaviour and enhanced multifunctional performance for environmental, energy and medical applications, but excluding device aspects.
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