{"title":"Inside Front Cover: Indole-Quinoline Transmutation Enabled by Formal Rhodium-Carbynoid (Angew. Chem. 25/2025)","authors":"Lu-Jie Liu, Meng-Yang Tian, Zhi-Yu Lang, Yong-Li Wang, Chun-Yang He, Yong-Zheng Chen, Wen-Yong Han","doi":"10.1002/ange.202510007","DOIUrl":null,"url":null,"abstract":"<p>Skeletal editing can rapidly forge valuable derivatives from parent molecule by late-stage simple transformations. In their Communication (e202501966), Wen-Yong Han et al. developed a Rh<sub>2</sub>(esp)<sub>2</sub>-catalyzed indole-quinoline transmutation using an α-diazotrifluoroethyl sulfonium salt, wherein the formal trifluoromethyl Rh-carbynoid (CF<sub>3</sub>C<sup>+</sup> = Rh), a trifluoromethyl cationic carbyne (CF<sub>3</sub>C<sup>+</sup>:) equivalent, was involved.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 25","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510007","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202510007","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Skeletal editing can rapidly forge valuable derivatives from parent molecule by late-stage simple transformations. In their Communication (e202501966), Wen-Yong Han et al. developed a Rh2(esp)2-catalyzed indole-quinoline transmutation using an α-diazotrifluoroethyl sulfonium salt, wherein the formal trifluoromethyl Rh-carbynoid (CF3C+ = Rh), a trifluoromethyl cationic carbyne (CF3C+:) equivalent, was involved.
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