{"title":"Metal-doped carbon dots for sensing applications in food analysis: A critical review","authors":"Kawan F. Kayani","doi":"10.1016/j.microc.2025.114296","DOIUrl":null,"url":null,"abstract":"<div><div>Food safety has become a significant global issue, leading to a growing demand for the rapid detection of both nutritional components and contaminants in food. Fluorescent sensing based on nanomaterials holds great promise for the development of advanced detection methods in food safety analysis. Doping is a powerful technique for modifying the physicochemical properties of carbon dots (CDs) and has gained considerable attention in recent years. Compared to non-metallic atoms, metal ions possess additional electrons, a larger atomic radius, and vacant orbitals. As a result, doping CDs with metal ions can significantly alter their electronic, optical, and magnetic properties by influencing electron density distribution and energy band gaps. This review explores the synthesis methods of metal ion-doped CDs (M-CDs) and discusses their applications in food sensing, covering key areas such as the detection of veterinary drug residues, food additives, anthrax biomarkers, heavy metals and ions, pesticide residues, dyes, and other compounds. Furthermore, the challenges related to the synthesis of M-CDs are discussed, along with insights into their prospective advancements in food analysis.</div></div>","PeriodicalId":391,"journal":{"name":"Microchemical Journal","volume":"215 ","pages":"Article 114296"},"PeriodicalIF":4.9000,"publicationDate":"2025-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Microchemical Journal","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0026265X25016509","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ANALYTICAL","Score":null,"Total":0}
引用次数: 0
Abstract
Food safety has become a significant global issue, leading to a growing demand for the rapid detection of both nutritional components and contaminants in food. Fluorescent sensing based on nanomaterials holds great promise for the development of advanced detection methods in food safety analysis. Doping is a powerful technique for modifying the physicochemical properties of carbon dots (CDs) and has gained considerable attention in recent years. Compared to non-metallic atoms, metal ions possess additional electrons, a larger atomic radius, and vacant orbitals. As a result, doping CDs with metal ions can significantly alter their electronic, optical, and magnetic properties by influencing electron density distribution and energy band gaps. This review explores the synthesis methods of metal ion-doped CDs (M-CDs) and discusses their applications in food sensing, covering key areas such as the detection of veterinary drug residues, food additives, anthrax biomarkers, heavy metals and ions, pesticide residues, dyes, and other compounds. Furthermore, the challenges related to the synthesis of M-CDs are discussed, along with insights into their prospective advancements in food analysis.
期刊介绍:
The Microchemical Journal is a peer reviewed journal devoted to all aspects and phases of analytical chemistry and chemical analysis. The Microchemical Journal publishes articles which are at the forefront of modern analytical chemistry and cover innovations in the techniques to the finest possible limits. This includes fundamental aspects, instrumentation, new developments, innovative and novel methods and applications including environmental and clinical field.
Traditional classical analytical methods such as spectrophotometry and titrimetry as well as established instrumentation methods such as flame and graphite furnace atomic absorption spectrometry, gas chromatography, and modified glassy or carbon electrode electrochemical methods will be considered, provided they show significant improvements and novelty compared to the established methods.