Non-explosive spalling UHPC mediated by synergistic regulation of thermal stress and vapor pressure

IF 14.2 1区 材料科学 Q1 ENGINEERING, MULTIDISCIPLINARY
Zhen Han , Jijun Miao , Yafei Yu , Dongshuai Hou , Chao Liu , Xiaohan Zhang , Zongjin Li , Ditao Niu , Xinpeng Wang
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Abstract

The explosive spalling of UHPC critically limits its application in fire-prone scenarios such as tunnels and nuclear facilities. Addressing the theoretical gap of thermal stress effect in existing studies, this research uncovers the synergistic damage mechanism of thermal stress and vapor pressure through experiments and thermo-mechanical coupled modeling. This research leverages polyethylene fiber (PEF) phase transitions to concurrently alleviate vapor pressure and thermal stress. A 12-min temperature plateau (the cross-section temperature stabilized at 155 ± 2 °C) suggest that PEF has a beneficial effect on thermal stress. Meanwhile, the melting and vaporization of PEF introduce extra pore channels with total porosity of 5.89 % at 400 °C for vapor pressure dissipation. Consequently, PEF-modified UHPC eliminates explosive spalling at 1000 °C, while the compressive strengths are maintained at 98.3 MPa and 36.0 MPa under 400 °C and 800 °C, respectively. Moreover, a spherical pore theory inspired model has been established to quantitatively validate that the synergistic regulation, where the results reveal that thermal stress and vapor pressure contribute 43.6 % and 56.4 % to the explosive spalling. This research proposes a novel approach to eliminate the explosive spalling, achieving theoretical breakthroughs for the fire-safe design of UHPC.
热应力和蒸汽压协同调节介导的非爆炸性剥落
超高压混凝土的爆炸剥落严重限制了其在隧道和核设施等火灾易发场合的应用。针对现有研究中热应力效应的理论空白,本研究通过实验和热-力耦合建模,揭示了热应力与蒸汽压的协同损伤机理。本研究利用聚乙烯纤维(PEF)相变同时缓解蒸汽压力和热应力。12分钟的温度平台(截面温度稳定在155±2°C)表明PEF对热应力有有益的影响。同时,PEF的熔化和汽化在400℃时引入了额外的孔隙通道,总孔隙率为5.89%。因此,pef改性的UHPC在1000℃时可消除爆炸剥落,而在400℃和800℃时抗压强度分别保持在98.3 MPa和36.0 MPa。此外,还建立了球形孔理论模型,定量验证了热应力和蒸汽压对爆炸剥落的协同调节作用,结果表明热应力和蒸汽压对爆炸剥落的影响分别为43.6%和56.4%。本研究提出了一种消除爆炸剥落的新方法,为UHPC防火设计实现了理论突破。
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来源期刊
Composites Part B: Engineering
Composites Part B: Engineering 工程技术-材料科学:复合
CiteScore
24.40
自引率
11.50%
发文量
784
审稿时长
21 days
期刊介绍: Composites Part B: Engineering is a journal that publishes impactful research of high quality on composite materials. This research is supported by fundamental mechanics and materials science and engineering approaches. The targeted research can cover a wide range of length scales, ranging from nano to micro and meso, and even to the full product and structure level. The journal specifically focuses on engineering applications that involve high performance composites. These applications can range from low volume and high cost to high volume and low cost composite development. The main goal of the journal is to provide a platform for the prompt publication of original and high quality research. The emphasis is on design, development, modeling, validation, and manufacturing of engineering details and concepts. The journal welcomes both basic research papers and proposals for review articles. Authors are encouraged to address challenges across various application areas. These areas include, but are not limited to, aerospace, automotive, and other surface transportation. The journal also covers energy-related applications, with a focus on renewable energy. Other application areas include infrastructure, off-shore and maritime projects, health care technology, and recreational products.
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