Ni(OAc)2 Catalyzed N‐Formylation of Primary Sulfonamides Using Carbon Dioxide at Ambient Pressure

IF 2.5 3区化学 Q2 CHEMISTRY, ORGANIC

European Journal of Organic Chemistry Pub Date : 2025-06-16 DOI:10.1002/ejoc.202500369

David Izuchukwu Ugwu, Ganesh Chandra Upreti, Ashish Garg, Anand Singh

引用次数: 0

Abstract

A Ni(OAc)2 catalysed N‐formylation of primary sulfonamides using gaseous carbon dioxide is reported. A range of aromatic, heteroaromatic, and aliphatic sulfonamides were formylated under ambient pressure of carbon dioxide in a closed system. This redox neutral method represents a mechanistically novel and operationally convenient method for employing carbon dioxide as a formyl equivalent.

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常压下Ni(OAc)2催化伯胺N -甲酰化反应的研究

本文报道了用气态二氧化碳催化A - Ni(OAc)2催化伯胺N -甲酰化反应。一系列芳香族、杂芳香族和脂肪族磺胺类化合物在二氧化碳的环境压力下在封闭系统中甲酰化。这种氧化还原中性方法代表了一种机械新颖和操作方便的方法，用于将二氧化碳作为甲酰基当量。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

European Journal of Organic Chemistry 化学-有机化学

CiteScore

5.40

自引率

3.60%

发文量

752

审稿时长

1 months

期刊介绍： The European Journal of Organic Chemistry (2019 ISI Impact Factor 2.889) publishes Full Papers, Communications, and Minireviews from the entire spectrum of synthetic organic, bioorganic and physical-organic chemistry. It is published on behalf of Chemistry Europe, an association of 16 European chemical societies. The following journals have been merged to form two leading journals, the European Journal of Organic Chemistry and the European Journal of Inorganic Chemistry: Liebigs Annalen Bulletin des Sociétés Chimiques Belges Bulletin de la Société Chimique de France Gazzetta Chimica Italiana Recueil des Travaux Chimiques des Pays-Bas Anales de Química Chimika Chronika Revista Portuguesa de Química ACH—Models in Chemistry Polish Journal of Chemistry.