Measurement of equilibrium potential of Cl2/Cl− redox couple in molten chlorides

IF 4.7 3区工程技术 Q2 ELECTROCHEMISTRY

Electrochemistry Communications Pub Date : 2025-06-10 DOI:10.1016/j.elecom.2025.107980

Zujian Tang , Qilin Yuan , Shangping Zhu , Osamu Takeda , Hongmin Zhu

引用次数: 0

Abstract

The current interruption method is used to determine the equilibrium potential of the Cl₂/Cl⁻ redox couple, and the theory behind the measurement is discussed. Different AgCl/Ag reference electrodes are prepared and calibrated by measuring the equilibrium potential of Cl₂/Cl⁻ redox couple. Cyclic voltammograms against the different AgCl/Ag reference electrodes before and after calibration in pure lithium chloride are reported, showing good agreement with thermodynamic calculations.

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熔融氯化物中Cl2/Cl−氧化还原偶对平衡电位的测定

采用电流中断法测定了Cl2/Cl−氧化还原对的平衡电位，并讨论了测量背后的理论。通过测量Cl2/Cl−氧化还原对的平衡电位，制备了不同的AgCl/Ag基准电极，并对其进行了标定。报道了在纯氯化锂中校准前后不同AgCl/Ag基准电极的循环伏安图，与热力学计算结果吻合良好。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Electrochemistry Communications 工程技术-电化学

CiteScore

8.50

自引率

3.70%

发文量

160

审稿时长

1.2 months

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