CuO-NiO-Embedded Guar Gum Hydrogel as an Efficient Catalyst for Dyes Removal.

IF 4.7 3区 工程技术 Q1 POLYMER SCIENCE
Polymers Pub Date : 2025-06-05 DOI:10.3390/polym17111577
Nujud Maslamani
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引用次数: 0

Abstract

In this work, Guar gum and copper oxide-nickel oxide (GG-CuO-NiO) hydrogel were produced with the help of formaldehyde solution to display an efficient catalytic performance toward the catalytic degradation of selected dyes (Methylene Blue (MB), Methyl Orange (MO), and Eosin Yellow (EY)) in the presence of NaBH4. The morphological and structural properties of the prepared hydrogel were thoroughly analyzed using SEM, EDX, XRD, and FT-IR techniques. According to the results, the GG-CuO-NiO hydrogel was able to reduce MB by 95% in one minute, 90.0% in four minutes, and 80.0% in 10 min for MO and EY, respectively. The catalytic efficiency of the hydrogel for MB was studied by adjusting its concentrations, varying reducing agent concentrations, and altering the amount of gel used. Using the recyclability method, which involved testing the GG-CuO-NiO hydrogel multiple times for the reduction of MB, the stability, reusability, and loss of catalytic activity of the hydrogel were examined. As a result, the designed GG-CuO-NiO hydrogel was stable for up to four times toward the reduction of MB. Lastly, the efficiency of the GG-CuO-NiO hydrogel was evaluated for MB removal in real samples and displayed exceptional reduction capabilities.

果镍包埋瓜尔胶水凝胶作为染料脱除的高效催化剂。
本研究在甲醛溶液的帮助下制备了瓜尔胶和氧化铜-氧化镍(GG-CuO-NiO)水凝胶,在NaBH4存在下对所选染料(亚甲基蓝(MB)、甲基橙(MO)和伊红黄(EY))进行了高效的催化降解。采用SEM、EDX、XRD、FT-IR等技术对制备的水凝胶进行了形貌和结构分析。结果表明,GG-CuO-NiO水凝胶对MO和EY的MB在1分钟内降低95%,4分钟内降低90.0%,10分钟内降低80.0%。通过调整水凝胶的浓度、改变还原剂的浓度和改变凝胶用量来研究水凝胶对MB的催化效率。采用可回收性方法,对GG-CuO-NiO水凝胶进行多次还原MB的测试,考察了水凝胶的稳定性、可重复使用性和催化活性损失。结果表明,所设计的GG-CuO-NiO水凝胶对MB的去除率高达4倍。最后,在实际样品中对GG-CuO-NiO水凝胶的去除率进行了评估,显示出优异的还原能力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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