{"title":"Modeling and application of temperature-dependent elastic constants in continuous fiber-reinforced shape memory polymer composites","authors":"Jiajun Chen, Chen Du, Wenwu Zhang, Penghui Zhu, Qinghu Wang, Xiongqi Peng","doi":"10.1016/j.polymertesting.2025.108882","DOIUrl":null,"url":null,"abstract":"<div><div>The mechanical properties of continuous fiber-reinforced shape memory polymer composites (SMPCs) exhibit a pronounced temperature dependence. However, exiting models for elastic constants are not specifically developed for SMPCs. In this study, analytical models based on a revised Eshelby's inclusion theory are developed to predict the temperature-dependent longitudinal, transverse, and flexural moduli of SMPCs. Experimental data from the literature, covering SMPCs with various fiber volume fractions (4.32 %, 6.36 % and 12.97 %), are used to validate the proposed models. Validation results show high predictive accuracy for flexural modulus across all fiber content systems, while predictions for longitudinal and transverse moduli exhibit limitations at the high fiber contents (12.97 %). To overcome these constraints, a refined Rule of Mixtures for longitudinal modulus and a revised Chamis model for transverse modulus are introduced. Further numerical investigations on several classic micromechanical models reveal that the revised Chamis formulation effectively captures the temperature-dependent evolution of shear modulus. Furthermore, by incorporating the concept of storage strain, these analytical models are implemented into the commercial finite element software ABAQUS via the UMAT subroutine, enabling finite element simulation of SMPC shape memory cycles. The recovery stress under different constraining strain is also numerically investigated. Overall, the results demonstrate the developed model's capability to predict the temperature-dependent elastic constants and shape memory behavior of SMPCs. This framework bridges critical gaps between micromechanical theory and macroscale SMPC performance, providing a robust tool for multi-physics-coupled smart structure design.</div></div>","PeriodicalId":20628,"journal":{"name":"Polymer Testing","volume":"150 ","pages":"Article 108882"},"PeriodicalIF":6.0000,"publicationDate":"2025-06-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Testing","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0142941825001965","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0
Abstract
The mechanical properties of continuous fiber-reinforced shape memory polymer composites (SMPCs) exhibit a pronounced temperature dependence. However, exiting models for elastic constants are not specifically developed for SMPCs. In this study, analytical models based on a revised Eshelby's inclusion theory are developed to predict the temperature-dependent longitudinal, transverse, and flexural moduli of SMPCs. Experimental data from the literature, covering SMPCs with various fiber volume fractions (4.32 %, 6.36 % and 12.97 %), are used to validate the proposed models. Validation results show high predictive accuracy for flexural modulus across all fiber content systems, while predictions for longitudinal and transverse moduli exhibit limitations at the high fiber contents (12.97 %). To overcome these constraints, a refined Rule of Mixtures for longitudinal modulus and a revised Chamis model for transverse modulus are introduced. Further numerical investigations on several classic micromechanical models reveal that the revised Chamis formulation effectively captures the temperature-dependent evolution of shear modulus. Furthermore, by incorporating the concept of storage strain, these analytical models are implemented into the commercial finite element software ABAQUS via the UMAT subroutine, enabling finite element simulation of SMPC shape memory cycles. The recovery stress under different constraining strain is also numerically investigated. Overall, the results demonstrate the developed model's capability to predict the temperature-dependent elastic constants and shape memory behavior of SMPCs. This framework bridges critical gaps between micromechanical theory and macroscale SMPC performance, providing a robust tool for multi-physics-coupled smart structure design.
期刊介绍:
Polymer Testing focuses on the testing, analysis and characterization of polymer materials, including both synthetic and natural or biobased polymers. Novel testing methods and the testing of novel polymeric materials in bulk, solution and dispersion is covered. In addition, we welcome the submission of the testing of polymeric materials for a wide range of applications and industrial products as well as nanoscale characterization.
The scope includes but is not limited to the following main topics:
Novel testing methods and Chemical analysis
• mechanical, thermal, electrical, chemical, imaging, spectroscopy, scattering and rheology
Physical properties and behaviour of novel polymer systems
• nanoscale properties, morphology, transport properties
Degradation and recycling of polymeric materials when combined with novel testing or characterization methods
• degradation, biodegradation, ageing and fire retardancy
Modelling and Simulation work will be only considered when it is linked to new or previously published experimental results.