Direct Observation of Clay Fabrics and Clay Pores in Naturally Faulted Shales

IF 5.2 3区 工程技术 Q2 ENERGY & FUELS
Yujiao Han, Hongjian Zhu*, Lipeng Yan, Hongye Feng* and Yanyan Pan, 
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Abstract

Clay fabrics and clay-hosted porosity, as the most essential components in shale gas reservoirs, are the result of a long succession of geological processes that range from sediment deposition and later diagenesis to tectonic activity. A high-resolution electron microscopy study on naturally faulted Longmaxi shales from the Southeast Sichuan Basin was conducted to understand the development of clay fabrics and their hosted pore network and place them in a tectonic context. The investigation demonstrates a significant uniformity between brittle deformation detected in the shale matrix with optical microscopy and slip deformation observed related to a strong degree of preferred alignment for clay particles documented with the scanning electron microscopy (SEM) fabric measurements. SEM and transmission electron microscopy (TEM) images reveal that clay pores are intimately linked to clay fabrics and are associated with grain slip deformation. Two major clay pore types can be identified and classified by their origin, which we named primary pores and secondary pores (SEP, tectonic origin). The majority of the primary pores are shelter pores (SHP), which are preserved due to the presence of pressure shadows that resist tectonic compaction and deformation, preventing pore structure collapse. SEP are linear nanometer-size openings that commonly have wider and elongated shapes and preferred orientations parallel to the clay foliation, and they constitute the bulk of available porosity. These findings offer new insight into the nature of clay-hosted porosity down to the nanoscale and explain microstructural deformation and porosity preservation of clay fabrics during faulting.

天然断裂页岩中粘土组构与粘土孔隙的直接观测
作为页岩气储层最重要的组成部分,粘土组构和粘土孔隙是一系列长期地质过程的结果,这些地质过程包括沉积作用、后期成岩作用和构造活动。利用高分辨率电子显微镜对川东南地区龙马溪天然断裂页岩进行了研究,了解了泥质组构及其赋存孔隙网络的发育情况,并将其置于构造背景下。研究表明,通过光学显微镜在页岩基质中检测到的脆性变形与扫描电子显微镜(SEM)织物测量记录的粘土颗粒的强烈优先排列所观察到的滑移变形之间存在显著的均匀性。扫描电镜(SEM)和透射电镜(TEM)图像显示,粘土孔隙与粘土织物密切相关,并与颗粒滑移变形有关。根据其成因可将粘土孔隙划分为原生孔隙和次生孔隙(SEP,构造成因)。原生孔隙主要为遮蔽孔隙(SHP),由于存在抗构造压实和变形的压力阴影而得以保存,防止孔隙结构坍塌。SEP是线性纳米尺寸的开口,通常具有更宽和更长的形状,并且优选平行于粘土片理的方向,它们构成了可用孔隙度的大部分。这些发现为研究纳米级黏土孔隙的性质提供了新的视角,并解释了断裂过程中黏土组构的微观结构变形和孔隙保存。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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