Samarium Diiodide/Samarium-Promoted Deoxygenative Dimerization of Unactivated Aldehydes and Ketones to Construct Internal Alkenes via C═O Bond Cleavage.

IF 3.3 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-06-10 DOI:10.1021/acs.joc.5c00010

Kexin Li, Yongqi Liang, Yongmei Cui, Chengwei Liu

引用次数: 0

Abstract

A samarium diiodide/samarium-promoted deoxygenative dimerization of unactivated aldehydes and ketones to construct alkenes under ligand-free and base-free conditions via C═O bond cleavage has been reported. Readily available unactivated aldehydes and ketones have been employed as substrates for preparing highly valuable internal alkenes. Wide substrate range and excellent functional group tolerance have been demonstrated to be a broad and robust method for the preparation of highly valuable alkenes.

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二碘化钐/钐促进非活性醛和酮通过C = O键裂解构建内烯烃的脱氧二聚反应。

本文报道了在无配体和无碱条件下，通过C = O键裂解，二碘化钐/钐促进非活性醛和酮的脱氧二聚化反应生成烯烃。易得的未活化醛和酮已被用作制备高价值内烯烃的底物。广泛的底物范围和优异的官能团耐受性已被证明是制备高价值烯烃的一种广泛而稳健的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.