Baolong Gong, Xiaoqing Ma, Tiange Wang, Jiale Hou, Shuxian Ji, Xixun Shen, Yulin Min, Qunjie Xu, Huaijie Cao
{"title":"Enhanced corrosion resistance of MXene/Zn-Al LDH coating on Al alloy under dry/humid and temperature alternating environments","authors":"Baolong Gong, Xiaoqing Ma, Tiange Wang, Jiale Hou, Shuxian Ji, Xixun Shen, Yulin Min, Qunjie Xu, Huaijie Cao","doi":"10.1016/j.corsci.2025.113088","DOIUrl":null,"url":null,"abstract":"<div><div>Herein, with strong physical barrier of Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene and ion-exchange ability of Zn-Al layer double hydroxide (LDH), MXene/LDH composite coating is designed on Al alloy to investigate the corrosion behaviors in dry/humid and temperature alternating environments. As a result, after alternating tests over 30 cycles, the MXene composite coating still possesses high corrosion resistance with a low corrosion current density of 4.86 × 10<sup>−8</sup> A/cm<sup>2</sup> in 3.5 wt% NaCl solution. Similarly, the coating exhibits stable corrosion resistance under temperature alternating environments. It is attributed to the impermeability and oxidation of MXene as well as the Cl<sup>-</sup> adsorption/trapping ability of Zn-Al LDH during the alternating cycles.</div></div>","PeriodicalId":290,"journal":{"name":"Corrosion Science","volume":"255 ","pages":"Article 113088"},"PeriodicalIF":7.4000,"publicationDate":"2025-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Corrosion Science","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0010938X25004159","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Herein, with strong physical barrier of Ti3C2Tx MXene and ion-exchange ability of Zn-Al layer double hydroxide (LDH), MXene/LDH composite coating is designed on Al alloy to investigate the corrosion behaviors in dry/humid and temperature alternating environments. As a result, after alternating tests over 30 cycles, the MXene composite coating still possesses high corrosion resistance with a low corrosion current density of 4.86 × 10−8 A/cm2 in 3.5 wt% NaCl solution. Similarly, the coating exhibits stable corrosion resistance under temperature alternating environments. It is attributed to the impermeability and oxidation of MXene as well as the Cl- adsorption/trapping ability of Zn-Al LDH during the alternating cycles.
期刊介绍:
Corrosion occurrence and its practical control encompass a vast array of scientific knowledge. Corrosion Science endeavors to serve as the conduit for the exchange of ideas, developments, and research across all facets of this field, encompassing both metallic and non-metallic corrosion. The scope of this international journal is broad and inclusive. Published papers span from highly theoretical inquiries to essentially practical applications, covering diverse areas such as high-temperature oxidation, passivity, anodic oxidation, biochemical corrosion, stress corrosion cracking, and corrosion control mechanisms and methodologies.
This journal publishes original papers and critical reviews across the spectrum of pure and applied corrosion, material degradation, and surface science and engineering. It serves as a crucial link connecting metallurgists, materials scientists, and researchers investigating corrosion and degradation phenomena. Join us in advancing knowledge and understanding in the vital field of corrosion science.