{"title":"rGO/Carbon composite-based electrocatalytic electrodes for efficient nitrate adsorption and reduction − current challenges and future perspective","authors":"Krishnan Vancheeswaran Prasad , Rachel Angeline Lenin , Mohanraj Kumar , Jih-Hsing Chang","doi":"10.1016/j.enmm.2025.101080","DOIUrl":null,"url":null,"abstract":"<div><div>The summary of this review paper addresses the pressing issue of nitrate contamination in water sources, increasing concern primarily due to agricultural runoff and industrial waste. Elevated nitrate levels pose significant risks to both human health, such as methemoglobinemia (blue baby syndrome), and aquatic ecosystems through processes like eutrophication. The paper examines the potential of carbon composite-based electrocatalytic electrodes, particularly those incorporating reduced graphene oxide (rGO), for effectively removing nitrates from contaminated water. The review uniquely contributes by analyzing nitrate reduction mechanisms, rGO’s catalytic role, electrode fabrication challenges, operational stability, pilot-scale implementation, and pathways for industrial adoption of rGO-based electrocatalysts. The high surface area of these materials makes them interesting, have superior conductivity, and excellent catalytic properties, which enhance their ability to adsorb and reduce nitrate ions. It demonstrates how major advancements in carbon composites have improved the effectiveness and selectivity of nitrate reduction, demonstrating their potential for real-world applications. However, challenges remain, particularly about scalability, the durability of the materials, and the unwanted production of by-products like ammonia during the reduction process. The further research is necessary to overcome these challenges by focusing on the development of more stable, scalable, and cost-effective materials. Reducing harmful by-products will also be essential for practical industrial applications. Advancements in this field will contribute to sustainable water treatment and the achievement of Sustainable Development Goal, which focuses on clean water and sanitation.</div></div>","PeriodicalId":11716,"journal":{"name":"Environmental Nanotechnology, Monitoring and Management","volume":"23 ","pages":"Article 101080"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Nanotechnology, Monitoring and Management","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2215153225000418","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Environmental Science","Score":null,"Total":0}
引用次数: 0
Abstract
The summary of this review paper addresses the pressing issue of nitrate contamination in water sources, increasing concern primarily due to agricultural runoff and industrial waste. Elevated nitrate levels pose significant risks to both human health, such as methemoglobinemia (blue baby syndrome), and aquatic ecosystems through processes like eutrophication. The paper examines the potential of carbon composite-based electrocatalytic electrodes, particularly those incorporating reduced graphene oxide (rGO), for effectively removing nitrates from contaminated water. The review uniquely contributes by analyzing nitrate reduction mechanisms, rGO’s catalytic role, electrode fabrication challenges, operational stability, pilot-scale implementation, and pathways for industrial adoption of rGO-based electrocatalysts. The high surface area of these materials makes them interesting, have superior conductivity, and excellent catalytic properties, which enhance their ability to adsorb and reduce nitrate ions. It demonstrates how major advancements in carbon composites have improved the effectiveness and selectivity of nitrate reduction, demonstrating their potential for real-world applications. However, challenges remain, particularly about scalability, the durability of the materials, and the unwanted production of by-products like ammonia during the reduction process. The further research is necessary to overcome these challenges by focusing on the development of more stable, scalable, and cost-effective materials. Reducing harmful by-products will also be essential for practical industrial applications. Advancements in this field will contribute to sustainable water treatment and the achievement of Sustainable Development Goal, which focuses on clean water and sanitation.
期刊介绍:
Environmental Nanotechnology, Monitoring and Management is a journal devoted to the publication of peer reviewed original research on environmental nanotechnologies, monitoring studies and management for water, soil , waste and human health samples. Critical review articles, short communications and scientific policy briefs are also welcome. The journal will include all environmental matrices except air. Nanomaterials were suggested as efficient cost-effective and environmental friendly alternative to existing treatment materials, from the standpoints of both resource conservation and environmental remediation. The journal aims to receive papers in the field of nanotechnology covering; Developments of new nanosorbents for: •Groundwater, drinking water and wastewater treatment •Remediation of contaminated sites •Assessment of novel nanotechnologies including sustainability and life cycle implications Monitoring and Management papers should cover the fields of: •Novel analytical methods applied to environmental and health samples •Fate and transport of pollutants in the environment •Case studies covering environmental monitoring and public health •Water and soil prevention and legislation •Industrial and hazardous waste- legislation, characterisation, management practices, minimization, treatment and disposal •Environmental management and remediation