Improved Efficiency of Carbon-Based Perovskite Solar Cells by Using Alternative Solvent for Doping-Free P3HT

IF 6 3区 工程技术 Q2 ENERGY & FUELS
Solar RRL Pub Date : 2025-05-13 DOI:10.1002/solr.202500108
Soe Ko Ko Aung, Hanmandlu Chintam, Priyabrata Sadhukhan, Bowen Yang, Gerrit Boschloo
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引用次数: 0

Abstract

Low-temperature-processed carbon-based perovskite solar cells (C-PSCs) are a potential candidate for industrial development, due to their low cost, high stability, and easy preparation methods. However, their power conversion efficiencies still lag behind that of metal-contact-based PSCs, due to poor compatibility of the carbon electrode with the underlying layers. Here, we introduce a doping-free poly(3-hexylthiophene) (P3HT) hole-transport layer deposited from chloroform to improve solar cell performance of PSCs that are prepared in ambient air. The resulting P3HT films have a lower roughness and a higher conductivity. A champion device with power conversion efficiency of 19.4% was obtained with negligible hysteresis and a remarkably enhanced fill factor (FF) of 80.2%. Unencapsulated devices maintained 70% of initial efficiency value after 350 hr under thermal stress at 85°C in dark and ambient air.

用无掺杂P3HT替代溶剂提高碳基钙钛矿太阳能电池效率
低温加工碳基钙钛矿太阳能电池(C-PSCs)具有成本低、稳定性高、制备方法简单等优点,具有潜在的工业发展潜力。然而,由于碳电极与底层的兼容性差,它们的功率转换效率仍然落后于基于金属接触的psc。在这里,我们引入了一种由氯仿沉积的无掺杂聚(3-己基噻吩)(P3HT)空穴传输层,以提高在环境空气中制备的PSCs的太阳能电池性能。所得的P3HT薄膜具有较低的粗糙度和较高的导电性。获得了功率转换效率为19.4%的冠军器件,迟滞可以忽略不计,填充因子(FF)显著提高至80.2%。未封装的器件在黑暗和环境空气中85°C的热应力下350小时后保持70%的初始效率值。
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来源期刊
Solar RRL
Solar RRL Physics and Astronomy-Atomic and Molecular Physics, and Optics
CiteScore
12.10
自引率
6.30%
发文量
460
期刊介绍: Solar RRL, formerly known as Rapid Research Letters, has evolved to embrace a broader and more encompassing format. We publish Research Articles and Reviews covering all facets of solar energy conversion. This includes, but is not limited to, photovoltaics and solar cells (both established and emerging systems), as well as the development, characterization, and optimization of materials and devices. Additionally, we cover topics such as photovoltaic modules and systems, their installation and deployment, photocatalysis, solar fuels, photothermal and photoelectrochemical solar energy conversion, energy distribution, grid issues, and other relevant aspects. Join us in exploring the latest advancements in solar energy conversion research.
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