Enrichment Mechanism of Organic Matter in the Marine–Continental Transitional Shale of the Taiyuan Formation in Ordos Basin, China: Control of the Paleoenvironment

IF 3.7 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Zhen He, Minfang Yang, Lei Wang, Jing Lu*, Ye Wang, Xue Peng and Longyi Shao, 
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Abstract

With the growing recognition of substantial exploration potential in transitional shale gas, increasing attention has been directed toward organic-matter-rich transitional shale. Although previous studies have primarily examined the characteristics of organic matter, basin depositional environments, and individual geochemical parameters, detailed analyses of depositional microfacies remain limited. Furthermore, the integration of geochemical analyses with sedimentological characteristics has been insufficient, leading to a limited understanding of the factors controlling the organic matter enrichment in transitional shale. This study focuses on the Taiyuan Formation in the Carboniferous-Permian Palougou section of the Ordos Basin. By employing an integrated approach comprising petrological and sedimentological analyses, major and trace element geochemistry, total organic carbon (TOC) content measurements, kerogen maceral identification, and scanning electron microscopy (SEM), we reconstructed four critical paleoenvironmental parameters: depositional environment, paleosalinity, paleoredox, and paleoproductivity. The findings provide insights into paleoenvironmental controls of the mechanisms of organic matter enrichment in transitional shale. Petrological and sedimentological data reveal seven distinct sedimentary microfacies in the transitional shale: upper delta plain flood lake, lower delta plain interdistributary bay, supratidal wetland, supratidal dryland, and intertidal, subtidal, and clastic offshore environments. A depositional model encompassing shallow-water delta, tidal flat, and offshore environments has been established, and it is found that the sedimentary environments in the study area responded to high-latitude glacial cycles. The evolution of the sedimentary environment, driven by late Paleozoic glaciations, is the primary factor influencing organic matter enrichment in the transitional shales of the study area, as it directly affects both the source and preservation conditions of shale organic matter. Specifically, flood lake and supratidal wetland environments are identified as the most favorable for organic matter enrichment, followed by the distributary bay and subtidal environments. Clarification of organic-rich intervals in transitional shale has important implications for future exploration and development of transitional shale gas.

鄂尔多斯盆地太原组海陆过渡页岩有机质富集机制:古环境控制
随着过渡型页岩气巨大的勘探潜力日益被人们所认识,富有机质过渡型页岩越来越受到人们的关注。虽然以往的研究主要考察了有机质特征、盆地沉积环境和单个地球化学参数,但对沉积微相的详细分析仍然有限。此外,地球化学分析与沉积学特征的结合还不够充分,导致对过渡期页岩有机质富集控制因素的认识有限。本文以鄂尔多斯盆地石炭-二叠系帕洛沟段太原组为研究对象。通过岩石学和沉积学分析、主微量元素地球化学、总有机碳(TOC)含量测定、干酪根显微组分鉴定和扫描电镜(SEM)等综合方法,重建了沉积环境、古盐度、古氧化还原和古生产力四个关键的古环境参数。这些发现为过渡型页岩有机质富集机制的古环境控制提供了新的思路。岩石学和沉积学资料显示,过渡期页岩有7种不同的沉积微相:上三角洲平原洪泛湖、下三角洲平原分流间湾、潮上湿地、潮上旱地、潮间带、潮下和碎屑近海环境。建立了浅水三角洲-潮滩-近海环境的沉积模式,发现研究区沉积环境响应高纬度冰川旋回。受晚古生代冰川作用驱动的沉积环境演化是影响研究区过渡性页岩有机质富集的首要因素,直接影响页岩有机质的来源和保存条件。其中,洪水湖和潮上湿地环境最有利于有机质富集,其次是分流湾和潮下环境。过渡型页岩富有机质层段的厘清对今后过渡型页岩气勘探开发具有重要意义。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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