Research on the Effects of Environmentally Friendly Additives on Mild Steel Electroless Plating

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Mugilan Kumar, Desikan Rajagopal and Sambantham Karthikeyan*, 
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Abstract

Using a nontoxic reducing agent, the corrosion behavior of an earthing electrode generated from a new and stable electroless copper–tin plating solution has been investigated. During the plating procedure, green additives such as moxifloxacin and gatifloxacin were utilized as stabilizers. Electrochemical methods and salt spray analysis proved that the electroless copper–tin-coated steel surface has exceptional corrosion resistance properties. The corrosion resistance was enhanced by the precipitation hardening (toughening) of surface coatings following heat treatment at 300 °C, which resulted in the production of intermetallic phases such as Cu3Sn and Cu6Sn5. The glossy structure of the coatings was revealed via SEM examinations. The data from the X-ray photoelectron spectral measurement showed that the binding energies 0.020 of the metallic components present in the preventive coatings demonstrated that the inner layer of the coatings contained Sn2 p3/2 and Sn2p accounted for high protection against corrosion resistance by this coatings methodology, and the outer layer of the coatings consisted of Cu3P, Cu2P3/2 O 1s, and O KLL. Electrochemical and quantum mechanical experiments were used to screen the additives’ performance.

环保添加剂对低碳钢化学镀的影响研究
采用无毒还原剂,研究了一种新型稳定化学镀铜锡液制备的接地电极的腐蚀行为。在电镀过程中,绿色添加剂如莫西沙星和加替沙星作为稳定剂。电化学方法和盐雾分析证明了化学镀铜锡钢表面具有优异的耐腐蚀性能。在300℃热处理后,涂层的析出硬化(增韧)增强了耐蚀性,产生了Cu3Sn和Cu6Sn5等金属间相。通过扫描电镜观察涂层的光滑结构。x射线光电子能谱测量结果表明,涂层中金属成分的结合能为0.020,表明涂层的内层含有Sn2、p3和Sn2p,涂层的外层含有Cu3P、cu2p3、2o和O - KLL。通过电化学和量子力学实验对添加剂的性能进行了筛选。
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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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