Visible-light mediated oxidative Diels-Alder reaction of hydroxylamines and 1,3-dienes

IF 2.1 3区化学 Q2 CHEMISTRY, ORGANIC

Tetrahedron Pub Date : 2025-05-27 DOI:10.1016/j.tet.2025.134752

Meijun Zhu , Lanqin Liu , Yujie Zhi , Hong Hou

引用次数: 0

Abstract

Visible-light-photoredox-catalyzed oxidative Diels-Alder reaction of hydroxylamines and 1,3-dienes was developed, accessing to various 3,6-dihydro-1,2-oxazines in good to excellent isolated yields. Distinct advantages, including mild reaction conditions, air as the terminal oxidant, as well as exceptional substrate tolerance with the present protocol.

查看原文本刊更多论文

可见光介导的羟胺和1,3-二烯氧化Diels-Alder反应

研究了羟胺与1,3-二烯在可见光-光氧化催化下的Diels-Alder氧化反应，得到了多种3,6-二氢-1,2-恶嗪，分离收率很高。明显的优势，包括温和的反应条件，空气作为终端氧化剂，以及特殊的底物耐受性与目前的方案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文求助全文

来源期刊

Tetrahedron 化学-有机化学

CiteScore

3.90

自引率

4.80%

发文量

439

审稿时长

34 days

期刊介绍： Tetrahedron publishes full accounts of research having outstanding significance in the broad field of organic chemistry and its related disciplines, such as organic materials and bio-organic chemistry. Regular papers in Tetrahedron are expected to represent detailed accounts of an original study having substantially greater scope and details than that found in a communication, as published in Tetrahedron Letters. Tetrahedron also publishes thematic collections of papers as special issues and ''Reports'', commissioned in-depth reviews providing a comprehensive overview of a research area.