Ricinodendron heudelotii Almond Extract as a Novel Green Corrosion Inhibitor for XC70 Steel in Acidic Medium

IF 1.9 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY
Katia Nasri, Nadia Ait Ahmed, Hamida Kermoune Issaadi, Ahmed Hichem Hamzaoui, Nabila Aliouane, Atmane Djermoune, Carine Chassigneux, Marielle Eyraud
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Abstract

In recent years, there has been growing interest in the use of safe, non-polluting substances, due to increased environmental awareness and stricter environmental protection regulations. This development has led to the emergence of a new class of corrosion inhibitors, known as green corrosion inhibitors. The present study aims to evaluate the inhibitory effect of different concentrations of Ricinodendron heudelotii (RHA) almond extract on the corrosion of XC70 mild steel in a 0.5 M hydrochloric acid (HCl) solution. The evaluation was performed using weight loss measurements, electrochemical techniques, and surface characterization methods. Potentiodynamic polarization tests revealed that RHA functions as a mixed-type inhibitor. Electrochemical impedance spectroscopy (EIS) tests showed that increasing the extract concentration leads to higher charge transfer resistance and lower double-layer capacitance. The adsorption of the inhibitor onto the steel surface followed the Langmuir isotherm model, and surface characterization confirmed the formation of a protective RHA layer. The results demonstrate that RHA is an effective corrosion inhibitor, achieving a maximum inhibition efficiency of 92% at a concentration of 1.2 g/L.

蓖麻杏仁提取物作为XC70钢在酸性介质中的新型绿色缓蚀剂
近年来,由于环保意识的增强和环保法规的严格,人们对使用安全、无污染的物质越来越感兴趣。这一发展导致了一类新的缓蚀剂的出现,被称为绿色缓蚀剂。研究了不同浓度的蓖麻籽杏仁提取物在0.5 M盐酸溶液中对XC70低碳钢腐蚀的抑制作用。评估使用失重测量、电化学技术和表面表征方法进行。动电位极化试验表明,RHA具有混合型抑制剂的作用。电化学阻抗谱(EIS)测试表明,萃取液浓度的增加导致电荷转移电阻增大,双层电容降低。抑制剂在钢表面的吸附遵循Langmuir等温线模型,表面表征证实了保护性RHA层的形成。结果表明,RHA是一种有效的缓蚀剂,在浓度为1.2 g/L时,其缓蚀效率最高可达92%。
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来源期刊
ChemistrySelect
ChemistrySelect Chemistry-General Chemistry
CiteScore
3.30
自引率
4.80%
发文量
1809
审稿时长
1.6 months
期刊介绍: ChemistrySelect is the latest journal from ChemPubSoc Europe and Wiley-VCH. It offers researchers a quality society-owned journal in which to publish their work in all areas of chemistry. Manuscripts are evaluated by active researchers to ensure they add meaningfully to the scientific literature, and those accepted are processed quickly to ensure rapid online publication.
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