Holistic green synthesis at room temperature of MIL-53(Al) from aluminum slag and application for glucose conversion to 5-hydroxymethylfurfural

IF 5.5 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Sustainable Chemistry and Pharmacy Pub Date : 2025-05-30 DOI:10.1016/j.scp.2025.102060

Guillermo Górtazar , Darío Fernández-González , Carmen Montoro , Jorge F. Romero , Anton Dafinov , Alejandro Jiménez , Ignacio Jiménez-Morales , Adrián Bogeat-Barroso , Félix Zamora , Mayra G. Álvarez , Elena López-Maya

引用次数: 0

Abstract

Herein, we report the first example of MOF synthesis employing aluminum slags as a waste resource. This synthesis was exclusively carried out from waste materials, under ambient conditions in water, thus aligning with the guiding principles of Green Chemistry. The resulting MIL-53(Al) material was further functionalized with SnO₂ nanoparticles and tested as catalyst for the dehydration of glucose to 5-hydroxymethylfurfural (5-HMF), showing a tenfold increase in catalytic efficiency compared to unsupported SnO₂.

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铝渣室温整体绿色合成MIL-53（Al）及其在葡萄糖转化为5-羟甲基糠醛中的应用

在此，我们报告了第一个以铝渣为废物资源合成MOF的例子。这种合成完全是在水中的环境条件下从废物中进行的，因此符合绿色化学的指导原则。得到的MIL-53（Al）材料被SnO2纳米粒子进一步功能化，并作为葡萄糖脱水成5-羟甲基糠醛（5-HMF）的催化剂进行了测试，结果表明，与未负载SnO2相比，催化效率提高了10倍。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Sustainable Chemistry and Pharmacy Environmental Science-Pollution

CiteScore

8.20

自引率

6.70%

发文量

274

审稿时长

37 days

期刊介绍： Sustainable Chemistry and Pharmacy publishes research that is related to chemistry, pharmacy and sustainability science in a forward oriented manner. It provides a unique forum for the publication of innovative research on the intersection and overlap of chemistry and pharmacy on the one hand and sustainability on the other hand. This includes contributions related to increasing sustainability of chemistry and pharmaceutical science and industries itself as well as their products in relation to the contribution of these to sustainability itself. As an interdisciplinary and transdisciplinary journal it addresses all sustainability related issues along the life cycle of chemical and pharmaceutical products form resource related topics until the end of life of products. This includes not only natural science based approaches and issues but also from humanities, social science and economics as far as they are dealing with sustainability related to chemistry and pharmacy. Sustainable Chemistry and Pharmacy aims at bridging between disciplines as well as developing and developed countries.