Analysis of low-frequency fatigue behavior of polyurethane elastomers under localized compressive loading using shear creep behavior

IF 5 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING
Doyoung Kim , Gayoung Kim , Jinhyeok Jang , Jae-Hyuk Choi , Munkyu Lee , Woong-Ryeol Yu
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Abstract

Polyurethane elastomers are widely utilized in various industrial applications due to their exceptional flexibility, energy absorption, and long-term pressure resistance. However, their mechanical stability under extremely low-frequency cyclic loading remains poorly understood, particularly in terms of fatigue and creep behavior. This study investigates the failure mechanisms of thermoplastic polyurethane (TPU) and cross-linked TPU under long-term localized compressive stress under extremely low-frequency cyclic loading, simulating real-world conditions in the automotive sector. The experimental approach includes dynamic mechanical analysis, tensile, compression, shear, fatigue, and creep tests, complemented by finite element simulations using a visco-hyperelastic model. Our findings indicate that shear stress plays a more significant role in TPU failure compared to compressive stress, with fatigue behavior under extremely low-frequency conditions exhibiting characteristics similar to creep deformation. The time-temperature superposition method was employed to accelerate testing, validating predictive models for long-term elastomer durability. Furthermore, the introduction of SiO2-reinforced TPU nanocomposites demonstrated enhanced shear creep resistance, effectively extending failure time under equivalent stress conditions. These results provide valuable insights for improving the design and reliability of polyurethane elastomers in applications requiring prolonged mechanical stability.
应用剪切蠕变特性分析局部压缩载荷作用下聚氨酯弹性体的低频疲劳行为
聚氨酯弹性体由于其优异的柔韧性、能量吸收和长期耐压性,在各种工业应用中得到广泛应用。然而,它们在极低频循环载荷下的机械稳定性仍然知之甚少,特别是在疲劳和蠕变行为方面。本研究研究了热塑性聚氨酯(TPU)和交联TPU在极低频循环载荷下长期局部压缩应力下的失效机制,模拟了汽车行业的实际情况。实验方法包括动态力学分析、拉伸、压缩、剪切、疲劳和蠕变测试,辅以使用粘超弹性模型的有限元模拟。我们的研究结果表明,与压应力相比,剪切应力在TPU失效中起着更重要的作用,在极低频条件下的疲劳行为表现出与蠕变变形相似的特征。采用时间-温度叠加法加速试验,验证弹性体长期耐久性预测模型。此外,二氧化硅增强TPU纳米复合材料的引入增强了抗剪切蠕变性能,有效延长了等效应力条件下的破坏时间。这些结果为在需要长时间机械稳定性的应用中改进聚氨酯弹性体的设计和可靠性提供了有价值的见解。
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来源期刊
Polymer Testing
Polymer Testing 工程技术-材料科学:表征与测试
CiteScore
10.70
自引率
5.90%
发文量
328
审稿时长
44 days
期刊介绍: Polymer Testing focuses on the testing, analysis and characterization of polymer materials, including both synthetic and natural or biobased polymers. Novel testing methods and the testing of novel polymeric materials in bulk, solution and dispersion is covered. In addition, we welcome the submission of the testing of polymeric materials for a wide range of applications and industrial products as well as nanoscale characterization. The scope includes but is not limited to the following main topics: Novel testing methods and Chemical analysis • mechanical, thermal, electrical, chemical, imaging, spectroscopy, scattering and rheology Physical properties and behaviour of novel polymer systems • nanoscale properties, morphology, transport properties Degradation and recycling of polymeric materials when combined with novel testing or characterization methods • degradation, biodegradation, ageing and fire retardancy Modelling and Simulation work will be only considered when it is linked to new or previously published experimental results.
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