Aromatic Tempering Unlocks the Unseen Bonding Behavior of Phosphorus/Boron FLPs at the Trade of Reactivity

IF 4.3 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-05-29 DOI:10.1021/acs.inorgchem.5c01847

Mohmmad Faizan, Shahil Yadav, Ravinder Pawar

引用次数: 0

Abstract

In FLP chemistry, (anti)aromatic modulation presents a compelling strategy for tuning the reactivity. This study explores previously unexamined (anti)aromatic modifications at the basic site in P/B-based IFLPs, revealing that aromatically modified phosphorus centers exhibit higher CO₂ activation energies due to an unconventional bonding mode, indicating a deviation from existing hypotheses. These findings offer complementary mechanistic insights and broaden the understanding of (anti)aromatic effects in IFLP systems.

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芳香族回火揭示了磷/硼FLPs在反应性交易中看不见的键合行为

在FLP化学中，（反）芳香调制提出了一种令人信服的调整反应性的策略。本研究探索了P/ b基IFLPs中先前未被研究过的（反）芳香修饰，发现芳香修饰的磷中心由于非常规的键合模式而表现出更高的CO2活化能，这表明与现有假设的偏差。这些发现提供了互补的机制见解，并拓宽了对IFLP系统中（抗）芳香效应的理解。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.