A Unified Equation for Predicting Crack Growth in Rubber Composites Across All Crack Growth Rates.

IF 4.7 3区 工程技术 Q1 POLYMER SCIENCE
Polymers Pub Date : 2025-05-15 DOI:10.3390/polym17101357
Aaron M Duncan, Keizo Akutagawa, Dimitrios G Papageorgiou, Julien L Ramier, James J C Busfield
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引用次数: 0

Abstract

The relationship between tearing energy and crack growth rates in elastomers is typically divided into three regions-slow crack growth, fast crack growth, and a transitional region-each described by separate power law relationships, requiring six variables to fully characterize the behavior. This study introduces a novel, unified equation that simplifies this relationship by combining two coexisting energy dissipation mechanisms into a single model with only four variables. The model consists of two terms, one for each energy dissipation mechanism: one term is dominant at slow crack growth rates and limited by a threshold energy, and the other is dominant at fast speeds. The transition region emerges naturally as the dominant mechanism shifts. The model's simplicity enables new advances, such as predicting fast crack growth tearing and transition energies using only slow crack growth data. This capability is demonstrated across a wide range of non-strain crystallizing rubbers, including filled and unfilled compounds, tested at room temperature and elevated temperatures and in both swollen and unswollen states. This model offers a practical tool for material design, failure prediction, and reducing experimental effort in characterizing elastomer performance. Notably, this is the first model to unify slow, transition, and fast crack growth regimes into a single continuous equation requiring only four variables, enabling the prediction of high-speed behavior using only low-speed experimental data-a major advantage over existing six-parameter models.

橡胶复合材料裂纹扩展预测的统一方程。
弹性体撕裂能与裂纹扩展速率之间的关系通常分为三个区域:慢裂纹扩展、快裂纹扩展和过渡区域,每个区域都由单独的幂律关系描述,需要六个变量来完全表征行为。本研究引入了一个新的统一方程,通过将两种共存的能量耗散机制合并为一个只有四个变量的单一模型,简化了这种关系。该模型由两项组成,每一项代表一种能量耗散机制:一项在裂纹扩展速度缓慢且受阈值能量限制时占优势,另一项在裂纹扩展速度较快时占优势。随着主导机制的转移,过渡区自然出现。该模型的简单性带来了新的进展,例如仅使用慢裂纹扩展数据预测快速裂纹扩展撕裂和转变能量。这种能力在各种非应变结晶橡胶中得到了证明,包括填充和未填充的化合物,在室温和高温下以及膨胀和未膨胀状态下进行了测试。该模型为材料设计、失效预测和减少表征弹性体性能的实验工作提供了实用的工具。值得注意的是,这是第一个将慢速、过渡和快速裂纹扩展机制统一为单一连续方程的模型,只需要四个变量,可以仅使用低速实验数据预测高速行为-这是现有六参数模型的主要优势。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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