{"title":"Electrical conductivity of low-doped ceria-based ceramics","authors":"Igor Zagaynov, Sergey V. Fedorov, Olga Antonova","doi":"10.1039/d4dt03165b","DOIUrl":null,"url":null,"abstract":"Ceria-based ceramic materials (M0.01Ce0.99O2) were successfully synthesized by the co-precipitation method and sintered at 1000 °C for 4 h in air. The electrical conductivity of these systems was measured by AC impedance spectroscopy at 500-750 °C in air; it has been established that the small introduction of dopants such as copper, bismuth, samarium, and neodymium increased this parameter by 4-5 times. However, the optimal dopants are Bi or Nd due to their higher conductivity and oxide ion transference number.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":"33 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d4dt03165b","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
Ceria-based ceramic materials (M0.01Ce0.99O2) were successfully synthesized by the co-precipitation method and sintered at 1000 °C for 4 h in air. The electrical conductivity of these systems was measured by AC impedance spectroscopy at 500-750 °C in air; it has been established that the small introduction of dopants such as copper, bismuth, samarium, and neodymium increased this parameter by 4-5 times. However, the optimal dopants are Bi or Nd due to their higher conductivity and oxide ion transference number.
期刊介绍:
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.