A Coordination Supramolecular Network Janus Separator Boost Sulfur Redox Dynamics in Lithium-Sulfur Batteries.

IF 10.7 2区 材料科学 Q1 CHEMISTRY, PHYSICAL
Zhao Chen, Yuanming Tan, Kaiji Lin, Shimei Lai, Chunshan Zhou, Shilin Huang, Yangyi Yang
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引用次数: 0

Abstract

Lithium-sulfur (Li-S) batteries are limited in practical application due to the dissolution and shuttle effect of lithium polysulfides (LiPSs) intermediates. Herein, a multifunctional Janus separator is designed that integrates the zirconium-based coordination supramolecular network (Zr-CSN) with the polypropylene (PP) membrane to fabricate Zr-CSN@PP. The Zr-CSN@PP constructs a barrier on the side of the sulfur cathode to block the passage of polysulfides, and the nanoporous structure of Zr-CSN transfers lithium ions quickly. The active zirconium sites and abundant oxygen-containing groups of Zr-CSN adsorb and catalyze the polysulfides effectively, which has been proved by experiments and theoretical calculations. Zr-CSN@PP promotes the migration of Li+ (the lithium-ion transference number is 0.63) and improves the kinetics of sulfur evolution reactions, enhancing the electrochemical performance of Li-S batteries. The Li-S battery with Zr-CSN@PP separator has a capacity of 650.63 mAh g-1 after 280 cycles at 0.5 C (average decay of 0.2% per cycle), and a capacity of 422.48 mAh g-1 after 400 cycles at 2 C. This concept of porous coordination supramolecular networks Janus separator provides a broad prospect for advanced Li-S batteries.

配位超分子网络Janus分离器提高锂硫电池中硫氧化还原动力学。
锂硫电池由于多硫化物锂(LiPSs)中间体的溶解和穿梭效应,在实际应用中受到限制。本文设计了一种多功能Janus分离器,将锆基配位超分子网络(Zr-CSN)与聚丙烯(PP)膜相结合,制备Zr-CSN@PP。Zr-CSN@PP在硫阴极一侧构建了屏障,阻止了多硫化物的通过,Zr-CSN的纳米孔结构可以快速转移锂离子。实验和理论计算证明,Zr-CSN的活性锆位点和丰富的含氧基团对多硫化物具有有效的吸附和催化作用。Zr-CSN@PP促进了Li+的迁移(锂离子迁移数为0.63),改善了析硫反应动力学,提高了Li- s电池的电化学性能。使用Zr-CSN@PP隔膜的Li-S电池在0.5 C下循环280次后的容量为650.63 mAh g-1(平均每循环衰减0.2%),在2 C下循环400次后的容量为422.48 mAh g-1。这种多孔配位超分子网络Janus隔膜的概念为先进的Li-S电池提供了广阔的前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Small Methods
Small Methods Materials Science-General Materials Science
CiteScore
17.40
自引率
1.60%
发文量
347
期刊介绍: Small Methods is a multidisciplinary journal that publishes groundbreaking research on methods relevant to nano- and microscale research. It welcomes contributions from the fields of materials science, biomedical science, chemistry, and physics, showcasing the latest advancements in experimental techniques. With a notable 2022 Impact Factor of 12.4 (Journal Citation Reports, Clarivate Analytics, 2023), Small Methods is recognized for its significant impact on the scientific community. The online ISSN for Small Methods is 2366-9608.
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