Development of commercial fully bio-based sport utility using jute/hemp bio-epoxy composite: Influence of stacking sequence on the fatigue, thermo-mechanical, vibrational and viscoelastic behavior
{"title":"Development of commercial fully bio-based sport utility using jute/hemp bio-epoxy composite: Influence of stacking sequence on the fatigue, thermo-mechanical, vibrational and viscoelastic behavior","authors":"Vinod Ayyappan, Vijay Raghunathan, Jiratti Tengsuthiwat, Sanjay Mavinkere Rangappa, Suchart Siengchin","doi":"10.1007/s10965-025-04428-7","DOIUrl":null,"url":null,"abstract":"<div><p>Eco-friendly composites are a key research focus due to environmental concerns, with natural fibers being explored as replacements for synthetic materials. This study aimed to develop and evaluate composites using commercially available jute and hemp fibers with a bio-epoxy matrix. Although there are various studies that report the mechanical properties of jute-hemp composites, no work has analyzed the complex dynamic mechanical, thermo-mechanical, fatigue, and vibrational properties of these bio-based jute-hemp bioepoxy composites. In this study, composites were developed using commercially available jute and hemp fibers, with bio-epoxy (SR-56) as the matrix to enhance eco-friendliness. Thermomechanical analysis revealed that the hemp-based composite had the lowest thermal expansion (0.12%) in the glass transition region. Dynamic mechanical analysis, performed under dual and single cantilever modes, showed that the jute-based composite exhibited the highest Tan δ value. The composite with hemp as the skin and jute as the core demonstrated intermediate values, with controlled Tan δ and complex modulus (E*). The E* of the HJH composite was 3.5 GPa in dual cantilever mode and 2.1 GPa in single cantilever mode due to localized stress concentration. Fatigue analysis showed an increase in stiffness from 30.04 N/mm at 40,000 cycles to 31.61 N/mm at 60,000 cycles before microcracks appeared at 90,000 cycles. Free vibration analysis indicated that composites reinforced with lower stiffness fibers had higher damping across all modes, with the JJJ composite exhibiting the highest damping ratios in mode-1 (0.56161), mode-2 (0.1664), and mode-3 (0.074891). These results demonstrate the potential of jute-hemp bio-epoxy composites for lightweight structural applications, demonstrated by the development of a bicycle mudguard using the optimal stacking sequence. </p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 6","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Polymer Research","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s10965-025-04428-7","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
引用次数: 0
Abstract
Eco-friendly composites are a key research focus due to environmental concerns, with natural fibers being explored as replacements for synthetic materials. This study aimed to develop and evaluate composites using commercially available jute and hemp fibers with a bio-epoxy matrix. Although there are various studies that report the mechanical properties of jute-hemp composites, no work has analyzed the complex dynamic mechanical, thermo-mechanical, fatigue, and vibrational properties of these bio-based jute-hemp bioepoxy composites. In this study, composites were developed using commercially available jute and hemp fibers, with bio-epoxy (SR-56) as the matrix to enhance eco-friendliness. Thermomechanical analysis revealed that the hemp-based composite had the lowest thermal expansion (0.12%) in the glass transition region. Dynamic mechanical analysis, performed under dual and single cantilever modes, showed that the jute-based composite exhibited the highest Tan δ value. The composite with hemp as the skin and jute as the core demonstrated intermediate values, with controlled Tan δ and complex modulus (E*). The E* of the HJH composite was 3.5 GPa in dual cantilever mode and 2.1 GPa in single cantilever mode due to localized stress concentration. Fatigue analysis showed an increase in stiffness from 30.04 N/mm at 40,000 cycles to 31.61 N/mm at 60,000 cycles before microcracks appeared at 90,000 cycles. Free vibration analysis indicated that composites reinforced with lower stiffness fibers had higher damping across all modes, with the JJJ composite exhibiting the highest damping ratios in mode-1 (0.56161), mode-2 (0.1664), and mode-3 (0.074891). These results demonstrate the potential of jute-hemp bio-epoxy composites for lightweight structural applications, demonstrated by the development of a bicycle mudguard using the optimal stacking sequence.
期刊介绍:
Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology.
As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including:
polymer synthesis;
polymer reactions;
polymerization kinetics;
polymer physics;
morphology;
structure-property relationships;
polymer analysis and characterization;
physical and mechanical properties;
electrical and optical properties;
polymer processing and rheology;
application of polymers;
supramolecular science of polymers;
polymer composites.